Petroleum Processing and Petrochemicals ›› 2018, Vol. 49 ›› Issue (5): 6-11.

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UPGRADING OF IDLE DIESEL HYDROGENATION UNIT FOR C5/C6 ISOMERIZATION AND INDUSTRIAL COMMERCIALIZATION

    

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  • Received:2017-10-09 Revised:2018-01-03 Online:2018-05-12 Published:2018-05-23
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Abstract: Appling the zeolitic C5/C6 isomerization technology developed by SINOPEC Research Institute of Petroleum Processing (RIPP), an idle 0.25 Mt/a diesel hydrotreating unit at ShanDong Dongming Petrochemical Grouphas been revamped to a C5/C6 isomerization unit. The feed is C5/C6 light naphtha and raffinate. from CCR unit。Based on principles of feeds’properties, maximum utilization on idle facilities and minimizing investment,the revamp proposed a deheptanizer for raffinate and a “DIP + Once-through” process for the isomerization, producing the C5/C6 isomerate gasoline with RON of 79.7.Unit performance test run indicates that the C5 and C6 isomerization rate of the zeolitic catalyst is 63.2% and 81.1%, respectively. The isomerate achieves an RON of 79.7 and a yield of 98.0%. All the operational results meet the technical control indices.The unit has provided a referential technical solution for the revamp of similar hydrotreating units.

Key words: C5/C6 isomerization, zeolite type isomerization catalyst, clean gasoline

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