UTILIZATION OF PHENOLIC COMPOUNDS IN LIGHT FRACTION OF FUSHUN SHALE OIL

Abstract

Abstract: The removal of phenolic compounds(P) in the Fushun shale oil (<280 ℃) was studied by using oxalic acid as catalyst and formaldehyde(F) as reaction reagent. The effects of mass ratio of phenol to formaldehyde, the ratio of m (P)/m (F)), catalyst dosage, condensation reaction time and temperature on the softening point and the dissolved viscosity of produced resin were investigated. The fourier transform infrared spectroscopy (FT-IR) and matrix-assisted laser desorption ionization time of flight mass spectrometry (MALDI-TOF-MS) were applied to analyze the phenolic resin. The results showed that at the conditions of the m(P)/m(F) =1:0.87, the catalyst dosage of 2%, the condensation reaction time of 6 h and the reaction temperature of 95 ℃, the removal efficiency of phenolic compounds reaches 87.94%. The dissolved viscosity of the resin is 63 mPa?s, with the softening point of 94 ℃, meeting the GB/T 30772-2014 requirements.

Key words: shale oil, phenol removal, phenol aldehyde reaction, binder

CLC Number:

References

[1]宋岩, 抚顺页岩油深加工工艺研究[D].吉林大学, 2012. [2]Li Q, Yang Z, Zou C.Shale Oil Geological Characteristics and Resource Potential of Mesozoic Yanchang Formation in Ordos Basin,North-Central China[J].Acta Geologica Sinica(English Edition), 2015, 89(A01):257-257 [3]Chen W, Jiang Z, Siyuan S U, et al.Discussion of Grading Evaluation Criteria to Study Shale Oil Resources in Zhanhua Sag[J].Acta Geologica Sinica, 2015, 89(S1):12-12 [4]Liu C, Wang Z, Guo Z, et al.Enrichment and distribution of shale oil in the Cretaceous Qingshankou Formation, Songliao Basin, Northeast China[J]. [J].Marine & Petroleum Geology, 2017, 86:751-770 [5]Somprasong Siramard.Oil Shale Pyrolysis under Non-conventional Conditions[D].中国科学院大学(中国科学院过程工程研究所), 2017. [6]耿层层, 李术元, 何继来.龙口页岩油中含氧化合物的分析与鉴定[J].燃料化学学报, 2012, 40(05):538-544 [7]侯吉礼, 马跃, 李术元, 藤锦生.世界油页岩资源的开发利用现状[J] [J].化工进展, 2015, 34(05):1183-1190 [8]. [9]Hang YU, Shuyuan LI, Jin G.Reaction conditions for catalytic hydrotreating of diesel distillate from Fushun shale oil[J].Acta Petrolei Sinica, 2010, 26(3):403-406 [10]Hirano K, Asami M.Phenolic resins—100 years of progress and their future[J].Reactive & Functional Polymers, 2013, 73(2):256-269 [11]杨燕红, 孙鸣, 代晓敏, 赵香龙, 马晓迅.基于酚醛反应的中低温煤焦油常压蒸馏馏分分离研究[J].煤化工, 2015, (06):30-34.[J].煤化工, 2015, (06):30-34 [12]任洪凯, 邓文安, 李传, 崔文龙.中/低温煤焦油酚类化合物的组成研究[J].[J].煤炭转化, 2013, (02):67-70 [13]Landau M.V, Herskowitz M, Givoni D, Laichter S, Yitzhaki D .Medium severity [14]hydrotreating and hydrocracking of Israeli shale oil[J].Fuel, 1998, 77(14).[J]., 1998,, 77(14):- [15]Luik H, Vink N, Lindaru E.Upgrading of estonian shale oil :1 Effect of hydrogenation on the chemical composition of Kukersite retort oil[J].Oil Shale, 1996, 13(3):193-196 [16]Williams P T, Chishti H M.Reaction of nitrogen and sulphur compounds during catalytic hydrotreatment of shale oil[J].Fuel, 2001, 80(7):957-963 [17]Yu H, Li S Y, Jin G Z, et al.Hydrotreating of the diesel distillate from Huadian shale oil for production of clean fuel[J].Journal of Fuel Chemistry & Technology, 2010, 38(3):297-301 [18]徐明, 陈登峰, 肖双全, 解民, 郝磊.大庆页岩油脱氮工艺实验研究[J].石油学报石油加工, 2012, 28(01):55-59 [19]Pang K, Hou Y, Wu W, et al.Efficient separation of phenols from oils via forming deep eutectic solvents[J].Green Chemistry, 2012, 14(9):2398-2401 [20]Lemon R C.Handbook of Industrial Toxicology[J].British Journal of Industrial Medicine, 1977, 34(3):235- [21]Zuorro A, Maffei G, Lavecchia R.Reuse potential of artichoke (Cynara scolimus, L.) waste for the recovery of phenolic compounds and bioenergy[J]. Journal of Cleaner Production, 2015, 111.[J].Journal of Cleaner Production, 2015, :111-111 [22]高振楠.煤液化油中酚类化合物的提取利用研究[J].[J].煤炭学报, 2010, 35(07):88-1192 [23]. [24]葛宜掌, 金红.Ba2+离子沉淀法回收酚类化学过程的研究[J]. [J].燃料化学学报, 1996, (3):266-270 [25]葛长涛.醇胺离子液体萃取分离中低温煤焦油中酚类化合物的研究[D].北京化工大学, 2013.