PETROLEUM PROCESSING AND PETROCHEMICALS ›› 2026, Vol. 57 ›› Issue (5): 36-43.
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Abstract: Taking the catalytic cracking (FCC) slurry from a certain petrochemical company as the raw material, a combined process of hydroupgrading and distillate cutting is employed. The test results show that the optimal process conditions for hydroprocessing are as follows:a reaction temperature of 320 ℃,a reaction pressure of 8 MPa,a volumetric space velocity of 0.6 h-1, and a hydrogen-to-oil volume ratio of 1000.The distillation fractionation of the hydrogenation product is carried out, and the fraction between 400 ℃ and 540 ℃ can be used as a high-quality aromatic rubber plasticizer.The yield of this product is 37.53%, the CA (thepercentage of carbon atoms on the aromatic ring to the total number of carbon atoms) is 21.92%, and the mass fraction of PCA is 2.90%.The product properties all comply with the standards of GB/T 33322 for product A1820.The comparative analysis of the Fourier transform infrared spectroscopy (FT-IR) and nuclear magnetic resonance hydrogen spectroscopy (1H-NMR) spectra of the products revealed that most of the polycyclic aromatic hydrocarbons in the feedstock oil underwent side-chain hydrogenation cracking and hydrogenation saturation reactions, converting into short-side-chain alkane molecules, and the product structure gradually became stable.
Key words: hydroupgrading, distillate cutting, polycyclic aromatic hydrocarbons, rubber plastizing agent
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http://www.sylzyhg.com/EN/Y2026/V57/I5/36