关键词: 甲醇, 催化裂化催化剂, 反应规律, 低碳烯烃

Abstract: The process of methanol to olefins on four kinds of FCC industrial equilibrium agents, LOSA-1 assistant and SAPO-34 was studied using the pulse microreacter-chromatography devices in the experiment. The results indicated: the hydrocarbon and light olefins yields of methanol conversion were 19.91% and 11.41% on GOR-Ⅱ, 21.90% and 16.52% on SAPO-34, 26.73% and 12.01% on LOSA-1. The hydrocarbon and light olefins yields reached a maximum value 27.52% and 15.72% when LOSA-1 was added into GOR-Ⅱat the ratio of 5%. The hydrocarbon and light olefins yields of 40% methanol solution were 9.09% and 6.20% on GOR-Ⅱ, 24.71% and 20.08% on SAPO-34. But the hydrocarbon and light olefins yields of methanol conversion were low on CHZ-4, DACS-GQ1 and RAG-10 and they can reach 11.12% and 6.04% in the case of increasing the amount of RAG-10.The experiment showed that the hydrocarbon and light olefins yields of methanol conversion were higher on GOR-Ⅱthan on other three kinds of FCC industrial equilibrium agents, the hydrocarbon and the light olefins yields of methanol increased when the LOSA-1 was added into GOR-Ⅱ.Therefore, preliminary reference was provided for the research of the reaction regularity of methanol to olefins on FCC catalysts.

Key words: methanol, catalytic cracking catalysts, reaction regularity, light olefins