石油炼制与化工 ›› 2020, Vol. 51 ›› Issue (11): 17-21.

• 加工工艺 • 上一篇    下一篇

煤基加氢裂化尾油溶剂抽提脱除多环芳烃的研究

孙显锋,王丹君,辛金妮,乔婧,闵小建   

  1. 陕西煤业化工技术研究院有限责任公司国家能源煤炭分质清洁转化重点实验室
  • 收稿日期:2020-04-23 修回日期:2020-06-08 出版日期:2020-11-12 发布日期:2020-11-24
  • 通讯作者: 孙显锋 E-mail:737370562@qq.com
  • 基金资助:
    陕西省重点研发计划

RESEARCH OF REMOVAL OF POLYCYCLIC AROMATIC HYDROCARBONS FROM COAL-BASED HYDROCRACKING TAIL OIL BY SOLVENT EXTRACTION

    

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  • Received:2020-04-23 Revised:2020-06-08 Online:2020-11-12 Published:2020-11-24
  • Supported by:
     

摘要: 以煤基加氢裂化尾油为原料、糠醛为抽提溶剂,采用溶剂抽提的方法开展了脱除多环芳烃的研究,考察了抽提温度、剂油质量比、抽提级数对抽余油收率及多环芳烃脱除率的影响。结果表明:单级抽提中,随着抽提温度升高或剂油质量比的增大,抽余油的收率不断减小、多环芳烃脱除率不断增大;二级、三级逆流抽提中,所得抽余油中多环芳烃脱除率均大于72.0%、多环芳烃质量分数均小于3.0%、抽余油收率均大于70.0%,同时,抽余油中未被抽提的单环、双环芳烃含量较高,其芳碳率CA均大于10.0%,有助于生产环保型煤基橡胶填充油。

关键词: 溶剂抽提, 加氢裂化尾油, 多环芳烃, 糠醛

Abstract: Furfural was used as extraction solvent to remove the polycyclic aromatics (PCA) from the coal-based hydrocracking tail oil. The effect of extraction temperature, ratio of solvent to oil and extraction stages on the yield and the removal rate of PCA in raffinate oil was investigated. With single-stage extraction process, increasing the extraction temperature or the ratio of the solvent to feed resulted in reduction of the raffinate yield and increase of the removal rate of PCA. The removal rates of PCA of the raffinate were both more than 72.0% and the yields of the raffinate were both more than 70.0% in two-stage and three-stage counter-current extraction processes. Meanwhile, the raffinate oil still had high content of unextracted monocyclic and bicyclic aromatics and the aromatic carbon rate CA was greater than 10.0%, which is conducive to the production of co-friendly coal-based rubber oils.

Key words: solvent extraction, hydrocracking tail oil, polycyclic aromatics, furfural

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