石油炼制与化工 ›› 2024, Vol. 55 ›› Issue (2): 121-127.

• 综述 • 上一篇    下一篇

基于工业化应用视角的低浓度甲烷催化燃烧催化剂研究进展

徐鑫1,李志1,齐健2,严媛1,杨鹏飞1,黄岚1   

  1. 1. 应急管理部信息研究院
    2. 中国科学院过程工程研究所 生化工程国家重点实验室
  • 收稿日期:2023-11-15 修回日期:2023-11-02 出版日期:2024-02-12 发布日期:2024-01-29
  • 通讯作者: 徐鑫 E-mail:xx8382368@163.com
  • 基金资助:
    应急管理部信息研究院科技创新发展项目;煤与煤层气共采国家重点实验室开放基金

RESEARCH PROGRESS ON CATALYTIC COMBUSTION CATALYSTS FOR LOW-CONCENTRATION METHANE FROM THE PERSPECTIVE OF INDUSTRIAL APPLICATION

  • Received:2023-11-15 Revised:2023-11-02 Online:2024-02-12 Published:2024-01-29

摘要: 甲烷是具有快速增温效应的短寿命强势温室气体,我国以井工开采为主的煤矿开采方式使煤矿甲烷成为我国能源活动甲烷排放的最主要来源,但目前针对低浓度甲烷仍没有高效的利用方式。甲烷催化燃烧可在较低温度下将甲烷完全转化为二氧化碳,是一种高效、环保的利用方式,有利于减少资源能源浪费,兼具环境、安全和能源效益。甲烷分子具有较高的结构稳定性,尤其是低浓度甲烷在温和条件下催化燃烧更具挑战性。基于工业应用视角,围绕实际工况条件对催化剂的要求,重点从催化剂的活性、热稳定性、机械稳定性和抗毒稳定性等4个方面的研究进展进行综述,分析甲烷催化燃烧催化剂应用面临的难点及未来发展趋势,旨在为开发适用于工业化应用的乏风瓦斯甲烷催化燃烧催化剂研究提供参考借鉴。

关键词: 低浓度甲烷, 催化燃烧, 催化剂

Abstract: Methane is a strong greenhouse gas with a short life span and rapid warming effect. Coal mining, which mainly consists of underground mining, makes coal mine methane become the main source of methane emission from energy activities in China. However, there is still no efficient method to utilize low-concentration methane. Catalytic combustion of methane can completely convert methane to carbon dioxide at a lower temperature, which is an efficient and environmentally friendly utilization method to use methane. Methane molecules have high structural stability, especially the catalytic combustion of low-concentration methane under mild conditions is more challenging. In this paper, based on the industrial application perspective, focusing on the requirements of actual working conditions for catalysts, the research progress in four aspects of catalyst activity, thermal stability, mechanical stability and anti-toxicity stability was overviewed, and the challenges in the application of methane-catalytic combustion catalysts and future development trend were analyzed. The purpose of this paper is to provide a reference for the development of catalytic combustion catalysts of ventilation air methane in coal mines for industrial applications.

Key words: low-concentration methane, catalytic combustion, catalyst