石油炼制与化工 ›› 2025, Vol. 56 ›› Issue (6): 95-99.

• 加工工艺 • 上一篇    下一篇

直馏柴油加氢改质生产优质乙烯原料技术的工业应用

梅智鹏1,王明华2,陈伟雄2,张奎3,任亮3   

  1. 1. 福建炼油化工有限公司
    2. 福建联合石化有限公司
    3. 中石化石油化工科学研究院有限公司
  • 收稿日期:2024-12-19 修回日期:2025-01-02 出版日期:2025-06-12 发布日期:2025-05-30
  • 通讯作者: 梅智鹏 E-mail:meizhp.fjlh@sinopec.com

COMMERCIAL APPLICATION OF HYDRO-UPGRADING TECHNOLOGY FOR PRODUCING HIGH-QUALITY ETHYLENE FEEDSTOCK FROM STRAIGHT RUN DIESEL


  • Received:2024-12-19 Revised:2025-01-02 Online:2025-06-12 Published:2025-05-30

摘要: 为了满足蒸汽裂解制乙烯装置对优质原料的需求,中石化石油化工科学研究院有限公司开发了第一代最大量生产优质乙烯原料(MHUG-E)技术及其专用催化剂,采用该技术得到的柴油和轻石脑油馏分均可作为优质乙烯原料。福建联合石化有限公司采用MHUG-E技术加工直馏柴油,在转化率仅为9.5%的情况下,所得柴油馏分的链烷烃质量分数从47.5%提高至55.7%,芳烃指数(BMCI)从29.5降低到18.7,是优质的乙烯原料。工业装置长周期运转结果显示,全周期工业装置进料稳定,连续运转70个月,催化剂失活缓慢,柴油产品十六烷指数大于55,BMCI为19左右,既是优质的国Ⅵ清洁柴油,又可作为优质的乙烯原料。

关键词: 乙烯, MHUG-E, 加氢改质, 直馏柴油

Abstract: In order to meet the demand for high-quality raw materials in steam-crackedethyleneunits, SINOPEC Research Institute of Petroleum Processing Co.,Ltd.(RIPP) had developed the first generation of cost-effective MHUG-E technology and catalyst. The diesel and light naphtha fractions produced by using this technology can be used as high-quality ethylene raw materials. Fujiang Refining & Petrochemical Company Limited (FREP) uses MHUG-E technology to process straight run diesel. The product diesel shows a high-quality steam-crackedethylene raw material, with a conversion rate of only 9.5%, the mass fraction of paraffin of the product diesel increased from 47.5% to 55.7%, and the BMCI value decreased from 29.5 to 18.7. The results of long-term industrial operation show that the industrial equipment has been running stably for 70 months, with a very slow catalyst deactivation rate. The diesel product has a cetane index greater than 55, which is not only a high-quality national Ⅵclean diesel, but also a high-quality steam-cracked ethyleneraw material.

Key words: ethylene, MHUG-E, hydroupgrading, straight run diesel