石油炼制与化工 ›› 2026, Vol. 57 ›› Issue (2): 62-67.

• 综述 • 上一篇    下一篇

丙烷脱氢制丙烯催化体系的研究进展

陈自娇,马娅娟,杨蒙,郭勤,苗鹏杰   

  1. 新疆理工学院能源化工工程学院
  • 收稿日期:2025-09-01 修回日期:2025-09-19 出版日期:2026-02-12 发布日期:2026-01-27
  • 通讯作者: 杨蒙 E-mail:2896647310@qq.com
  • 基金资助:
    SiO2纳米纤维原位晶化ZSM-5沸石及对MTP性能及抗积碳机制研究

RESEARCH PROGRESS ON CATALYTIC SYSTEMS FOR PROPANE DEHYDROGENATION TO PROPYLENE

  • Received:2025-09-01 Revised:2025-09-19 Online:2026-02-12 Published:2026-01-27

摘要: 在全球丙烯需求持续增长及碳中和目标驱动下,丙烷脱氢(PDH)凭借其显著节能优势,成为丙烯生产的重要路线。近年来,催化剂设计与反应工程均取得关键突破:Pt基催化剂通过动态活性位调控实现高选择性与稳定性,通过分子筛限域策略可有效抑制Pt烧结;非贵金属Co基催化剂在降低成本的同时保持高活性。反应工程方面,化学链供氧与氢燃烧耦合技术突破了热力学平衡限制,实现了能量高效循环,智能化集成工艺显著降低了碳排放。未来需聚焦多尺度模拟、反应器-催化剂协同设计、绿电耦合等方向,推动PDH技术向低碳化、高性能发展,支撑烯烃产业绿色转型。

关键词: 丙烷脱氢, 丙烯, 催化剂

Abstract: Against the backdrop of continuously growing global propylene demand and the drive toward carbon neutrality, propane dehydrogenation (PDH) has emerged as a key route for propylene production due to its significant energy-saving advantages. In recent years, critical breakthroughs have been achieved in both catalyst design and reaction engineering: Pt-based catalysts achieve high selectivity and long-term stability through dynamic active site regulation; the zeolite confinement strategy effectively suppresses sintering; non-noble metal Co-based catalysts maintain high activity while reducing costs. In terms of reaction engineering, the chemical looping oxygen supply coupled with hydrogen combustion technology has broken through the thermodynamic equilibrium limitation, enabling efficient energy recycling, and intelligent integrated processes have significantly reduced carbon emissions. Future efforts should focus on directions such as multiscale simulation, reactor-catalyst synergistic design, and green electricity coupling to promote the development of PDH technology towards low carbonization and high performance, thereby supporting the green transformation of the olefin industry.

Key words: propane dehydrogenation, propylene, catalyst