石油炼制与化工 ›› 2026, Vol. 58 ›› Issue (7): 57-63.

• 催化剂 • 上一篇    下一篇

增产碳四烯烃助剂在重油催化裂化装置的工业应用

朱伟1,金亮1,官劲松1,刘雨晴2,于善青2,严加松2   

  1. 1. 中国石化荆门分公司
    2. 中石化石油化工科学研究院有限公司
  • 收稿日期:2025-12-16 修回日期:2026-03-10 出版日期:2026-07-12 发布日期:2026-06-29
  • 通讯作者: 刘雨晴 E-mail:liuyuqing.ripp@sinopec.com

COMMERCIAL APPLICATION OF AN ADDITIVE FOR INCREASING C4 OLEFIN IN HEAVY OIL CATALYTIC CRACKING UNIT

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  • Received:2025-12-16 Revised:2026-03-10 Online:2026-07-12 Published:2026-06-29

摘要: 中石化石油化工科学研究院有限公司开发的HBC-B催化助剂兼具重油转化能力和丁烯选择性,不以牺牲汽油收率为代价增产丁烯。在中国石化荆门石化公司2.80 Mt/a重油催化裂化装置上进行了工业应用,结果表明:当HBC-B助剂占系统催化剂藏量4.5%时,总丁烯收率由4.55%增至5.20%,提高0.65百分点,增幅14.3%;液化气中总丁烯体积分数增加2.60百分点;液化气收率增加0.39百分点,油浆和焦炭总产率降低0.43百分点,汽油和液化气总收率增加,汽油辛烷值略有提高。工业应用结果证实HBC-B助剂增产丁烯效果优异,可为具有增产丁烯需求的催化裂化装置提供参考。

关键词: 重油催化裂化, 催化助剂, 丁烯

Abstract: The HBC-B catalytic additive developed by SINOPEC Research Institute of Petroleum Processing Co., Ltd. exhibits both robust heavy oil conversion capability and exceptional butylene selectivity, enabling increased butylene production without compromising gasoline yield. The industrial trial was conducted on the 2.80 Mt/a heavy oil fluid catalytic cracking (FCC) unit of SINOPEC Jingmen Petrochemical Company. The results revealed that when HBC-B constituted 4.5% of the total catalyst inventory, the overall butylene yield improved from 4.55% to 5.20%, representing a 0.65 percentage point increase (14.3% growth). Concurrently, the volume fraction of butylene in LPG rose by 2.60 percentage points while LPG yield itself increased by 0.39 percentage points. Notably, the combined production rate of slurry oil and coke decreased by 0.43 percentage points, resulting in an overall increase in the combined yield of gasoline and LPG, accompanied by a slight improvement in gasoline octane number. The commercial application results have confirmed that the HBC-B additive exhibits excellent performance in increasing butylene production, providing a reference for FCC units with a demand for boosting butylene.

Key words: heavy oil catalytic cracking, catalytic additive, butylene