石油炼制与化工 ›› 2026, Vol. 57 ›› Issue (9): 17-25.

• 加工工艺 • 上一篇    下一篇

催化裂化汽油降苯的机理洞察与综合解决方案

孙敏1,徐志成1,宋海涛1,王云2,包斌洋3,沈兴2,沈宁元1   

  1. 1. 中石化石油化工科学研究院有限公司
    2. 中国石化催化剂有限公司
    3. 中国石油克拉玛依石化分公司
  • 收稿日期:2025-11-18 修回日期:2026-04-01 出版日期:2026-09-12 发布日期:2026-08-21
  • 通讯作者: 徐志成 E-mail:xuzc1970@126.com

MECHANISTIC INSIGHTS AND COMPREHENSIVE SOLUTIONS FOR BENZENE REDUCTION IN FCC GASOLINE

  • Received:2025-11-18 Revised:2026-04-01 Online:2026-09-12 Published:2026-08-21

摘要: 随着环保法规的日益严苛,特别是国Ⅵ汽油标准的实施,催化裂化汽油作为我国车用汽油的主要调合组分,其苯含量的控制成为炼油企业亟待解决的关键问题。深入剖析了催化裂化反应过程中苯的生成机理,明确了芳烃迁移反应与芳烃生成反应是其两大主要来源。在此基础上,系统分析了催化裂化原料性质、反应工艺类型、操作参数及催化剂性质等因素对汽油苯含量的影响规律。从工业应用角度,综述了原料优化、操作调整、催化剂类型选择、工艺技术改造及调合优化等降苯措施以及应用效果,为炼油企业优化工艺提供理论依据和技术参考。

关键词: 催化裂化, 汽油, 苯含量, 生成机理, 影响因素, 降苯措施

Abstract: As environmental regulations become increasingly stringent, particularly with the implementation of the National Ⅵ gasoline standard, fluid catalytic cracking (FCC) gasoline—serving as the primary blending component for automotive gasoline in China—has made the control of its benzene content a critical issue that refining enterprises must urgently address. This paper provides an in-depth analysis of the formation mechanism of benzene during the FCC reaction process, identifying alkylaromatic transfer reactions and aromatics formation reactions as its two major sources. On this basis, it systematically examines the influence of factors such as FCC feedstock properties, reaction process types, operating parameters, and catalyst characteristics on the benzene content in gasoline. From an industrial application perspective, this review summarizes various benzene reduction measures—including feedstock optimization, operational adjustments, catalyst selection, process technological upgrades, and blending optimization,along with their application effects, thereby providing theoretical foundations and technical references for refining enterprises to optimize their processes.

Key words: catalytic cracking, gasoline, benzene content, formation mechanism, influencing factors, benzene reduction measures