石油炼制与化工 ›› 2026, Vol. 57 ›› Issue (10): 78-83.

• 加工工艺 • 上一篇    下一篇

石油基碳材料工业化生产

宋以常1,宋慎聪2   

  1. 1. 中国石化北京燕山分公司
    2. 国网北京市电力公司通州供电公司
  • 收稿日期:2026-01-21 修回日期:2026-05-28 出版日期:2026-10-12 发布日期:2026-09-20
  • 通讯作者: 宋以常 E-mail:songyc.yssh@sinopec.com

INDUSTRIAL PRODUCTION OF PETROLEUM-BASED CARBON MATERIALS

  • Received:2026-01-21 Revised:2026-05-28 Online:2026-10-12 Published:2026-09-20

摘要: 在新能源加速替代成品油的背景下,我国北方某炼化企业致力于石油基高端碳材料的开发,延迟焦化装置以低金属含量、低硫(及含硫)原油所产低硫减压渣油和催化裂化油浆为原料,通过调整焦炭塔生焦周期和加热炉出口温度等手段,可稳定生产满足下游用户要求的预焙阳极用石油焦和负极焦。生产负极焦时选择镍、钒含量低的中间基偏石蜡基低硫原油,所产减压渣油饱和分质量分数低于20%,芳香分质量分数大于40%,沥青质质量分数低于5%;延迟焦化装置适当掺炼催化裂化油浆,控制加热炉出口温度约495 ℃,焦炭塔生焦周期为24 h。

关键词: 石油焦, 碳材料, 负极焦, 延迟焦化

Abstract: A delayed coking unit, using low-sulfur vacuum residue derived from low-metal, low-sulfur, and sulfur-containing crude oils together with fluid catalytic cracking (FCC) slurry oil as feedstocks, can stably produce prebaked anode-grade petroleum coke and negative electrode coke that meet downstream users' requirements by adjusting operating parameters such as the coke drum coking cycle and the heater outlet temperature.During the production of negative electrode coke, a low-sulfur crude oil of an intermediate base with a paraffinic tendency, characterized by low nickel and vanadium contents, is selected, such that the resulting vacuum residue has a saturates mass fraction below 20%, an aromatics mass fraction above 40%, and an asphaltenes mass fraction below 5%. In the delayed coking unit, an appropriate amount of FCC slurry oil is blended into the feed, the heater outlet temperature is controlled at approximately 495 ℃, and the coke drum coking cycle is set to 24 h.

Key words: petroleum coke, carbon material, anode-grade coke, delayed coking