石油炼制与化工

• 基础研究 • 上一篇    下一篇

四氯乙烷的吸附热力学和动力学研究

樊秀菊1,朱建华2,武本成3,赵向苗3   

  1. 1. 中国石油大学(北京)化学工程学院
    2. 中国石油大学(北京)化学科学与工程学院
    3. 中国石油大学(北京)化学工程学院
  • 收稿日期:2010-10-26 修回日期:1900-01-01 出版日期:2011-06-12 发布日期:2011-06-12
  • 通讯作者: 樊秀菊

THE THERMODYNAMICS AND DYNAMICS FOR THE ADSORPTION REMOVAL OF TETRACHLOROETHANE

Xiangmiao Zhao   

  • Received:2010-10-26 Revised:1900-01-01 Online:2011-06-12 Published:2011-06-12

摘要: 通过静态吸附实验,研究了四氯乙烷在吸附剂M上的吸附热力学和动力学特性。研究结果表明:四氯乙烷在吸附剂M上的吸附等温线属于典型的L型吸附曲线,吸附剂M对四氯乙烷的吸附符合Langmuir吸附等温方程,吸附可以自发进行,吸附过程为放热过程,属于物理吸附;吸附剂M对四氯乙烷的吸附动力学可用拟二级动力学方程描述,随温度升高,初始吸附速率以及吸附速率常数均呈现增大趋势。

关键词: 四氯乙烷, 吸附, 热力学, 动力学

Abstract: The thermodynamic and kinetic characteristics of adsorbing tetrachloroethane on adsorbent M were studied via static adsorption experiments. The experimental results show that the adsorption isotherm of adsorbing tetrachloroethane on adsorbent M is a typical L type adsorption curve, and this adsorption process agrees well with the Langmuir adsorption equation. The thermodynamic parameters illustrate that the absorption of tetrachloroethane on adsorbent M could happen spontaneously, it is an exothermic process attributed to physical adsorption. The dynamics of adsorbing tetrachloroethane on adsorbent M could be described by pseudo-second order kinetic equation. With the increase of adsorption temperature, the initial adsorption rate and adsorption rate constant exhibit an increase tendency.

Key words: Tetrachloroethane, Adsorption, Thermodynamics, Dynamics