石油炼制与化工

• 加工工艺 •    下一篇

环保型芳烃橡胶填充油抽提工艺开发与工业应用

王玉章1,吴艳萍2,施昌智1,刘颖荣1   

  1. 1. 石油化工科学研究院
    2. 中国石化济南分公司
  • 收稿日期:2011-03-14 修回日期:2011-03-22 出版日期:2011-07-12 发布日期:2011-07-12
  • 通讯作者: 王玉章

DEVELOPMENT AND COMMERCIAL APPLICATION OF AN EXTRACTION PROCESS FOR PRODUCING ENVIRONMENTAL FRIENDLY AROMATIC RUBBER EXTENDER OIL

  • Received:2011-03-14 Revised:2011-03-22 Online:2011-07-12 Published:2011-07-12

摘要: 以富含芳烃的溶剂精制抽出油为原料,筛选出对多环芳烃具有选择性溶解能力的抽提溶剂,开发了ARE环保型芳烃橡胶填充油抽提工艺,在中型ARE装置上生产出满足欧盟环保指标要求的芳烃橡胶填充油。根据石油化工科学研究院开发的ARE抽提工艺数据包,济南分公司建设了70kt/a 环保型芳烃橡胶填充油生产装置。生产结果表明,溶剂精制抽出油经ARE溶剂抽提可以生产满足欧盟环保指标要求的芳烃橡胶填充油,橡胶充油后得到的SBR1723橡胶性能优良,各项指标均达到SBR1723优级品标准。

关键词: 芳烃, 橡胶, 填充油, 抽提, 苯并芘

Abstract: An extraction process for producing aromatic rubber extender oil was developed and named as ARE process by using a screened out high selective solvent to extract polycyclic aromatic hydrocarbons from aromatic-rich extracts. On a pilot plant four aromatic-rich extracts were used as feedstocks and relative four aromatic rubber extender oil (ARE oil) samples were obtained. The qualities of these ARE oil samples satisfied the requirements of European Directive 2005/69/EC. Later, an ARE unit with 70 kt/a capacity was set up in SINOPEC Jinan Company based on the ARE extraction process package developed by Research Institute of Petroleum Processing, and the produced environmental friendly ARE oil well met the requirements of European Directive 2005/69/EC. Results of rubber extending oil test showed that the qualities of ARE oil-extended rubber met the super grade specifications of SBR 1723 Rubber Standard perfectly.

Key words: aromatics, rubber, extender oil, extraction, benzopyrene