石油炼制与化工

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C8芳烃异构化技术的选择研究

张惠跃 刘中勋 王建伟   

  1. 中国石化上海股份有限公司 石油化工科学研究院
  • 收稿日期:2007-12-26 修回日期:1900-01-01 出版日期:2008-06-12 发布日期:2008-06-12
  • 通讯作者: 刘中勋

STUDY ON THE SELECTION OF C8 AROMATICS ISOMERIZATION TECHNOLOGY

  

  • Received:2007-12-26 Revised:1900-01-01 Online:2008-06-12 Published:2008-06-12

摘要: 阐述了乙苯脱乙基型和乙苯转化型C8芳烃异构化催化剂在反应活性、工艺条件、产品分布和处理量等方面的技术特点,结合上海石化新建600 kt/a芳烃联合装置项目情况,从催化剂的性能、联合装置物料平衡的测算结果、对二甲苯产出率等方面对不同技术路线进行了比较分析,在充分考虑原料特点的前提下,确定上海石化新建芳烃联合装置选择使用脱乙基型C8芳烃异构化催化剂。经济分析结果表明,所选技术路线具有装置投资省、目标产品生产成本相对较低的特点。

关键词: 催化剂, 8碳, 芳烃, 异构化

Abstract: Comparison between two types of C8 aromatics isomerization catalysts, ethylbenzene (EB) dealkylation catalyst and EB conversion catalyst, in the aspects of reaction activity, operation conditions, product distributions and processing capacity were described. A selection of technologies was discussed for the 60×104 t/a new integrated aromatics complex of Shanghai Petrochemical Company based on the conditions of the integrated unit, feed properties, catalyst performance, estimated material balance results and yield of para-xylene, finally, technology with EB dealkylation catalyst was adopted. It was concluded by the economic analysis data that technology with EB dealkylation catalyst required less equipment investment and could provide lower production cost for the objective product.

Key words: catalyst, 8 carbon, aromatic hydrocarbon, isomerization