石油炼制与化工

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HF-101原油脱钙剂的工业应用研究

张花 张宇 刘红燕 王丽芬   

  1. 天津大港油田油田化学有限公司 天津大港油田油田化学有限公司 天津大港油田油田化学有限公司 中国石油锦州石化分公司
  • 收稿日期:2009-07-20 修回日期:1900-01-01 出版日期:2010-01-12 发布日期:2010-01-12
  • 通讯作者: 张花

STUDY ON THE COMMERCIAL APPLICATION OF HF-101 DECALCIFICATION AGENT FOR CRUDE OIL

  

  • Received:2009-07-20 Revised:1900-01-01 Online:2010-01-12 Published:2010-01-12

摘要: 采用大港油田集团油田化学有限公司研制的HF-101脱钙剂对中国石油锦州石化分公司炼油厂掺炼的杜巴原油脱钙效果进行了实验室评价及工业试验。实验室评价结果表明,在剂钙比为2:1、注水量为5%、电脱盐温度130 ℃、破乳剂加量30 ?g/g的条件下原油脱钙率达到90.89%~91.43%,显示了良好的脱钙效果。工业应用试验结果表明,使用HF-101脱钙剂后原油中的钙平均脱除率可达到90.89%,脱后原油的平均钙含量为24.81 ?g/g;原油的灰分由脱钙前的0.065%降至0.030%左右;原油的盐含量和含水量也大幅度下降。并且使用HF-101脱钙剂可使电脱盐装置的操作电流下降50%,具有较好的节能降耗作用。

关键词: 原油, 脱钙剂, 电脱盐

Abstract: HF-101 decalcification agent developed by Dagang Petroleum Oilfield Chemicals Company was used to remove calcium from mixed Duba crude oil in Jinzhou Petrochemical Company, and its calcium removal performance was studied in laboratory and commercial unit. The laboratory test results showed that under the conditions of an agent to calcium mass ratio of 2, a water injection amount of 5%, an electrostatic desalt temperature of 130 ℃ and a demulsifier added dosage of 30 µg/g, the calcium removal rates of crude oil reached 90.89%~91.43%. Commercial trial results showed that using HF-101 agent the average calcium removal rate was 90.89%, the average calcium content of crude oil was 24.81 µg/g, the ash content of crude oil was reduced from 0.065% to 0.030%, the salt and water contents of the crude were reduced significantly. Besides, the operation electric current of the electrostatic desalt unit reduced about 50% when using HF-101 decalcification agent.

Key words: crude oil, decalcification agent, electrostatic desalt