石油炼制与化工

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XDS溶剂中压吸收脱除高酸性天然气中有机硫性能研究

章建华 沈本贤 刘纪昌 孙辉   

  1. 化学工程联合国家重点实验室(华东理工大学) 化学工程联合国家重点实验室(华东理工大学) 化学工程联合国家重点实验室(华东理工大学) 化学工程联合国家重点实验室(华东理工大学)
  • 收稿日期:2008-10-07 修回日期:1900-01-01 出版日期:2009-03-12 发布日期:2009-03-12
  • 通讯作者: 章建华

STUDY ON REMOVING ORGANOSULFUR COMPOUNDS FROM HIGH SOUR NATURAL GAS BY MEDIUM PRESSURE ABSORPTION USING XDS SOLVENT

Ben-xian Shen   

  • Received:2008-10-07 Revised:1900-01-01 Online:2009-03-12 Published:2009-03-12

摘要: 以具有工业应用背景的XDS为溶剂进行了1.5MPa压力下脱除模拟川东北高酸性天然气中有机硫等有害组分的研究,与MDEA溶剂的净化效果进行了对比,并对XDS溶剂脱除有机硫的机理进行了分析。在操作压力1.5MPa、温度40℃、气液体积比为126的条件下,MDEA溶剂吸收的净化气总硫含量符合二类气指标,而XDS溶剂的净化气H2S含量小于0.5mg/m3、总硫含量小于20mg/m3,达到一类气指标,表明XDS溶剂对天然气中有机硫的脱除效果明显优于MDEA溶剂。

关键词: 天然气, 有机硫, 脱硫剂, 吸收

Abstract: Using XDS solvent to remove organic sulfur compounds from high sour natural gas was investigated. Meanwhile, a comparison of the sulfur removal performance of XDS solvent and MDEA solvent was carried out and the sulfur removal mechanism of XDS solvent was discussed. Results showed that under the conditions of an operation pressure of 1.5Mpa, an absorption temperature of 40℃, a packing height of 600 mm and a gas to liquid ratio of 126, the contents of H2S and total sulfur in the treated gas of XDS solvent (both XDS-A and XDS-B) and MDEA solvent met the requirements of first class gas and second class gas, respectively. Furthermore, when using XDS-B solvent, even at a gas to liquid ratio of 169 the contents of H2S and total sulfur in the treated gas still met the first class gas requirements, which indicated that the sulfur removal performance of XDS solvent was better then that of MDEA solvent. As compared with XDS-B solvent, XDS-A solvent was more suitable for the deep purification under low gas to solvent ratio.

Key words: natural gas, organosulfur, desulfur solvent, absorption