石油炼制与化工
• 分析与评定 • 上一篇
蔺玉贵,田松柏
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TIAN Songbai
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摘要: 对四种测定原油蜡含量标准方法进行了比较,发现得到的结果差别明显,并具有一定的规律性。四种方法测定原油蜡含量的数值从大到小顺序为UOP 46> SY/T 0537 >SY/T 7550>ГОСТ 11851。产生这些差别的原因主要是四种标准方法的脱蜡条件及脱蜡溶剂的组成都有一些不同,每种脱蜡溶剂在相应脱蜡条件下对蜡的溶解性不同造成的。对所得蜡样品组成分析结果表明,蜡的溶解性差异主要来自于小于C25的正构烷烃和所有非正构烷烃。
关键词: 原油, 蜡, 分析方法
Abstract: Four standard methods (SY/T 0537, SY/T 7550, ГОСТ 11851 and UOP 46) for determining wax content in crude oil are compared. Significant differences and certain regularities among the wax content results obtained by these methods are observed. The wax contents obtained from high to low are in the order of UOP 46> SY/T 0537> SY/T 7550> ГОСТ 11851. It can be seen that in these four methods, the dewaxing conditions, solvent compositions and the solubility of wax in solvent are varied, which leads to the differences of results obtained by each method. Furthermore, based on the analysis of wax compositions it is found that the differences are mainly caused by the various solubilities of ≤C25 n-paraffins and other hydrocarbons in the individual solvent under individual dewaxing conditions.
Key words: crude oil, wax, analytical method
蔺玉贵,田松柏. 原油蜡含量测定方法比较[J]. 石油炼制与化工, doi: .
TIAN Songbai. COMPARISON OF METHODS FOR DETERMINING WAX CONTENT IN CRUDE OIL[J]. Petroleum Processing and Petrochemicals, doi: .
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