石油炼制与化工

• 催化剂 • 上一篇    下一篇

PS-Ⅵ连续重整催化剂工业运转性能跟踪

王以科 潘茂华   

  1. 镇海炼化分公司炼油一部 镇海炼化分公司炼油一部
  • 收稿日期:2007-12-17 修回日期:1900-01-01 出版日期:2008-07-12 发布日期:2008-07-12
  • 通讯作者: 王以科

PERFORMANCE OF COMMERCIAL RUNNING PS-VI CONTINUOUS REFORMING CATALYST

  

  • Received:2007-12-17 Revised:1900-01-01 Online:2008-07-12 Published:2008-07-12

摘要: 报道了由石油化工科学研究院开发的PS-VI连续重整催化剂在中国石化镇海炼化分公司800kt/a连续重整装置上工业应用试验寿命期内性能跟踪情况。结果表明,与原使用催化剂相比,初期PS-VI催化剂的芳烃产率提高6.46个百分点,稳定汽油收率提高1.32个百分点、氢气产率提高0.35个百分点、积炭速率降低26%以上;PS-VI催化剂具有良好的耐磨性能、活性稳定性、水热稳定性和持氯性能。与使用初期PS-VI催化剂相比,末期PS-VI催化剂由于杂质含量增加,加权床层入口温度(WAIT)提高4.8℃,稳定汽油收率下降1.28个百分点。

关键词: 催化重整, 催化剂, 工业规模, 再生

Abstract: PS-VI catalyst developed by Research Institute of Petroleum Processing was used in the 800 kt/a continuous catalyst regeneration reforming unit of Zhenhai Refining and Chemical Company. The commercial running results showed that PS-VI catalyst exhibited high resistant against attrition, good hydrothermal stability and chloride retention ability. As compared with the base catalyst, using PS-VI catalyst at the initial stage the yields of aromatics, reformate and hydrogen increased 6.46, 1.32 and 0.35 percentage points, respectively; the coke rate reduced more than 26%. As compared with the catalyst at the initial stage, at the end stage (after running 1 918 days) the catalyst activity slightly decreased due to the increase of impurities, the reformate yield dropped 1.28 percentage points.

Key words: catalytic reforming, catalyst, full scale, regeneration