石油炼制与化工

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基于RBF神经网络的乙醇脱水制乙烯反应条件优化

索红波 蒋晓 胡燚 苏国东   

  1. 南京工业大学 南京工业大学
  • 收稿日期:2009-08-03 修回日期:1900-01-01 出版日期:2010-03-12 发布日期:2010-03-12
  • 通讯作者: 胡燚

OPTIMIZATION OF THE REACTION CONDITIONS OF ETHANOL DEHYDRATION TO ETHYLENE BASED ON RBF NEURAL NETWORK SIMULATION

  

  • Received:2009-08-03 Revised:1900-01-01 Online:2010-03-12 Published:2010-03-12

摘要: 以La改性HZSM-5分子筛为乙醇脱水催化剂,采用正交实验设计确定实验点,考察原料液乙醇质量分数、反应温度、空速和催化剂粒径等四个因素对乙烯产率的影响。以正交实验结果作为训练样本,采用RBF神经网络对乙醇脱水生成乙烯的反应条件进行仿真模拟,并用穷举法求出最佳反应条件。结果表明,由神经网络仿真模拟出的三维图可以直观地体现各个反应条件对乙烯产率的影响。在反应温度250℃、空速0.5 h 1、原料液乙醇质量分数74%、催化剂70目的最佳反应条件下,神经网络模拟产率为98.87%,与实验结果97.12%基本吻合,相对误差为-1.77%。

关键词: 神经网络, 乙醇, 乙烯, 脱水

Abstract: Experiments of ethanol dehydration to ethylene over La modified HZSM-5 zeolite catalyst were carried out according to orthogonal design. The effects of ethanol mass fraction (in feed), reaction temperature, space velocity and catalyst particle size on the yield of ethylene were investigated. Based on the RBF neural network theory, a model simulated the process of ethanol dehydration to ethylene was established by using the above test data as training samples. Then the network system trained was used to predict the effects of various factors and their interactions on ethylene yield. Three-dimensional graphs produced by the network could effectively express the relationships between reaction conditions and catalytic activity. Under the optimal reaction conditions of a reaction temperature of 250 ℃, a space velocity of 0.5 h 1, an ethanol mass fraction (in feed) of 74% and a catalyst particle size of 70 mesh, the simulated ethylene yield was 98.87%, which was very close to the test result of 97.12% with a relative error of -1.77%.

Key words: neural network, ethanol, ethylene, dehydration