ADVANCES IN RESEARCHES ON AQUATHERMOLYSIS CATALYSTS FOR HEAVY CRUDE OILS

Abstract

Abstract: Catalytic aquathermolysis is one of the most potential recovery technologies for heavy crude oils. Advances in researches on aquathermolysis catalysts for heavy crude were summarized based on the importance and necessity of catalytic aquathermolysis for heavy crude recovery. Various catalysts were introduced in accordance with the development of techniques, and the develop tendency of catalyst and process was discussed as well. It seems that developing high activity catalyst system to conduct aquathermolysis of heavy crude under moderate reaction conditions is still the main research target; besides, combining aquathermolysis catalysts with other viscosity reduction methods and developing integrated complex viscosity reducing technologies to exploit synergetic effect should also be focused.

Key words: heavy crude oil, aquathermolysis, catalyst, developing tendency

References

[1] Hyne J B. Synopsis Report No.50,Aquathermolysis[R].A. C. No.11103103B/C[J].,1986,:- [2]Clark P D,Hyne J B.Studies on the chemical reactions of heavy oils under steam stimulation condition[J].AOSTRA J Res,1990,6(1):29-39 [3]Clark P D,Hyne J B,Tyrer J D.Chemistry of organo sulfur compound type occurring in heavy oil sands: 1High temperature hydrolysis and thermolysis of therahydrothiophene in relation to steam stimulation processes[J].Fuel,1983,62(5):959-962 [4]Clark P D,Hyne J B,Tyrer J D.Chemistry of organosulfur compound type occurring in heavy oil sands: 2Influence of pH on the high temperature hydrolysis of tetraothiophene and thiophene[J].Fuel,1984,63(1):125-128 [5]Clark P D,Hyne J B,Tyrer J D.Chemistry of organosulfur compound type occurring in heavy oil sands: 3Reaction of thiophene and tetrahydro thiophene with vanadyl and nickel salts[J].Fuel,1984,63(6):1645-1649 [6]Clark P D,Hyne J B,Tyrer J D.Chemistry of organosulfur compound type occurring in heavy oil sands: 4The high temperature reaction of hiophene and tetrahydro thiophene with aqueous solution of aluminium and first row transition metal cations[J].Fuel,1987,66(5):1353-1357 [7]Clark P D,Hyne J B,Tyrer J D.Chemistry of organosulfur compound type occurring in heavy oil sands: 5Reaction of thiophene and tetrahydro thiophene with aqueous group VIIIB metal species at high temperature[J].Fuel,1987,66(5):1699-1702 [8]范洪富，刘永建，赵晓非，等.金属盐对辽河稠油水热催化裂解反应影响研究[J].燃料化学学报,2001,29(05):430-433 [9]范洪富，马军.蒸汽和金属盐作用下稠油黏度的变化[J].油田化学,2006,23(02):150-152 [10]陈尔跃，刘永建，闻守斌.辽河稠油中胶质在催化水热裂解反应中的降解[J].石油与天然气化工,2006,35(1):49-50 [11]宋向华，蒲春生，刘洋，等.井下乳化/水热催化裂解复合降黏开采稠油技术研究[J].油田化学,2006,23(2):153-157 [12]王杰祥，樊泽霞，任熵，等.单家寺稠油催化水热裂解实验研究[J].油田化学,2006,23(3):205-208 [13]张弦，刘永建，罗鹏飞，等.水热裂解辅助蒸气吞吐强化辽河油田稠油开采的效果[J].大庆石油学院学报,2011,35(1):46-50 [14]陈尔跃，刘永建，梁敏，等.油溶性油酸镍对辽河稠油的降黏作用[J].大庆石油学院学报,2010,34(6):68-71 [15]张博，刘永建，赵法军，等.注蒸汽条件下稠油催化改质降黏实验研究[J].油田化学,2011,28(02):167-171 [16]刘永建，赵法军，赵国，等.稠油的甲酸供氢催化水热裂解改质实验研究[J].油田化学,2008,25(02):133-136 [17]韩梅.有机镍、铁催化剂对胜利稠油的催化降粘研究[D].厦门:厦门大学[J].[J].,2007,:- [18]夏菲，陈艳玲，吴川.芳基双希夫碱在低温稠油水热催化裂解中的室内研究[J].地质科技情报,2007,26(3):91-94 [19]中国地质大学(武汉)，克拉玛依市三达新技术开发有限责任公司.过渡金属磺酸盐络合物稠油水热催化降粘剂及其制备方法[J].CN201110036321.[J].3[P,2011,:- [20]西南石油大学.乙酰丙酮钼环糊精包合物的制备法及在稠油降粘中的应用[J].[J].CN1948349[P,2007,:- [21]西南石油大学.表面活性剂包裹乙酰丙酮钼催化剂的制备方法及其应用[J].[J].CN101007286[P,2007,:- [22]吴川，雷光伦，姚传进，等.双亲催化剂作用超稠油水热催化裂解降黏机理研究[J].燃料化学学报,2010,38(6):684-690 [23]中国地质大学(武汉).一种含有两亲结构的稠油水热催化裂解降粘剂的制备方法[J].[J].CN1944572[P,2007,:- [24]景萍. Ni2+掺杂改性的SO42-/ZrO2固体超强酸的制备及对胜利稠油的降粘作用[D].厦门:厦门大学[J].[J].,2007,:- [25]景萍，李清彪，韩梅，等.Ni2+和Sn2+改性的SO42-/ZrO2固体超强酸催化剂对稠油的降黏性能[J].石油化工,2007,36(3):237-241 [26]王元庆，陈艳玲，夏菲，等.用于稠油水热催化降黏的keggin型杂多酸盐的制备表征及应用[J].地质科技情报,2007,26(2):81-85 [27]闻守斌.胜利油田单6东超稠油脱硫降粘机理及现场实施方案研究[D].东营:大庆石油学院[J].[J].,2004,:- [28]闻守斌，刘永建，宋玉旺,等.硅钨酸对胜利油田超稠油的催化降黏作用[J].大庆石油学院学报,2004,28(1):25-27 [29]李伟，朱建华，齐建华.纳米Ni催化剂在超稠油水热催化裂解降黏中的应用研究[J].燃料化学学报,2007,35(2):176-180 [30]吴川，雷光伦，姚传进,等.纳米镍催化剂对胜利超稠油水热催化裂解降黏的影响[J].中国石油大学学报(自然科学版,2011,35(1):164-168 [31]范洪富，李忠宝.离子液体[BMIM]Br·FeCl3改质稠油实验研究[J].石油与天然气化工,2007,36(6):475-477 [32]范洪富，李忠宝，梁涛.离子液体催化改质稠油实验研究[J].燃料化学学报,2007,35(1):32-35 [33]樊泽霞，王腾飞，何玉海.离子液体对稠油的改质降黏作用影响因素研究[J].燃料化学学报,2009,37(6):690-693