Petroleum Processing and Petrochemicals ›› 2014, Vol. 45 ›› Issue (6): 74-78.
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Abstract: The 3rd generation ultra-low pressure continous catalytic reforming technology introduced from abroad with a ChlorsorbTM system is adopted in the newly built unit in Tianjin branch, SINOPEC using the PS-VI catalyst developed by RIPP. The PS-VI catalyst has a good chlorine adsorptive capacity, by which the dechlorination rate of the regeneration flue gas is up to 98%, meeting the request of the chlorine adsorption technology. However, the chlorine adsorption technology makes the water content increases largely in the regeneration circulating gas. This speeds up the reduction of catalyst specific surface, and causes the catalyst lifetime shortened and corrosion of the equipment seriously. After the technical transformation by using the solid dechlorination technology and GL-1 regeneration flue gas dechlorination agent, both developed by RIPP, the chlorine mass fraction of regeneration flue gas is reduced to less than 2μg/g. The decline trend of the specific surface area of PS-VI is returned to normal. The PS-VI catalyst lifetime is extended greatly.
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http://www.sylzyhg.com/EN/Y2014/V45/I6/74