Abstract: Sodium removal process of ZSM-5 zeolite was studied by bipolar membrane electrodialysis (EDBM). The results indicate that the zeolite with Na2O content less than 0.1% can be obtained by EDBM, meanwhile Si，Na and part of template agent can be recycled. The EDBM zeolite is equal to the ZSM-5 zeolite by NH4+ exchange method both in physicochemical properties and catalytic performance. The new process is eco-friendly with no ammonia or salty wastewater emission, and the water can be reused.

Key words: bipolar membrane electrodialysis, removal of sodium, recovery, template