Petroleum Processing and Petrochemicals ›› 2019, Vol. 50 ›› Issue (10): 46-51.

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PREPARATION OF MESOPOROUS Y ZEOLITE BY TEMPLATE METHOD AND ITS APPLICATION IN CATALYTIC CRACKING

Zhao Jun,Wang Genggeng,Hu Jie,Liu Baijun,Liu Dongfeng   

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  • Received:2019-01-25 Revised:2019-03-05 Online:2019-10-12 Published:2019-10-24
  • Contact: Zhao Jun E-mail:zjqz925@163.com
  • Supported by:
     

Abstract: The mesoporous Y zeolites were prepared by hydrothermal synthesis method with three block polymer(F127)or cationic surfactant cetyl trimethylammonium bromide(CTAB)as template. The samples were characterized by XRD,SEM,TEM,N2 adsorption and desorption,and NH3-TPD. The catalytic cracking properties of the catalysts synthesized were evaluated in a micro-activity test unit,and light diesel was used as feedstock. The results of XRD and SEM showed that the hierarchical Y zeolites prepared using template had no difference in the structure and morphology with conventional USY. The analysis of N2 adsorption and desorption isotherms and NH3-TPD demonstrated that the mesoporous volume and total acid sites increased with the addition of templates. Compared to conventional catalyst CAT,the catalyst F-MCAT preparaed by F-MUSY using F127 as templates exhibited a better catalytic cracking property,and the micro-activity was 3.89 percentage points higher than that without template. It is concluded that the abundant mesopores volume and appropriate acidity have a stimulating effect on catalytic activity.

Key words: Y zeolite, template method, mesoporous, catalytic cracking

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