Petroleum Processing and Petrochemicals ›› 2020, Vol. 51 ›› Issue (3): 38-42.

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COMMERCIAL APPLICATION OF DOMESTIC TiO2-BASED CLAUS CATALYST IN PURIFICAITON OF HIGH H2S CONTENT NATURAL GAS

Hu Liangpei,Zhang Wenbin,Du Li,Wei Jinghui,Huang Kun   

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  • Received:2019-08-30 Revised:2019-10-17 Online:2020-03-12 Published:2020-03-31
  • Contact: Hu Liangpei E-mail:421645229@qq.com
  • Supported by:
     

Abstract: The second unit with a capacity of 20 kt / a (122 series) for sulfur recovery in the No.2 complex unit of Natural Gas Purification Plant of SINOPEC Dazhou Natural Gas Purification Co., Ltd. has started industrial trials using domestic TiO2-based Claus catalyst LS-981G since April 2018. The practical results of the device running for one year showed that the catalyst LS-981G had a good performance, the total hydrolysis rate of carbonyl sulfur was above 98%, the total hydrolysis rate of carbon disulfide was 100%, and the total sulfur recovery rate was above 99.96%. The mass concentration of SO2 in the flue gas emission was less than 400 mg / m3, which is far lower than the reqirement(not exceeding 960 mg/m3)of the GB16297-1996 “Comprehensive Air Pollutant Emission Standard”.

Key words: TiO2 based Claus catalyst, sulfur recovery, sour gas, hydrogen sulfide, carbon disulfide, sulfur dioxide, carbonyl sulfide

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