PROGRESS IN N-FORMYLATION OF CARBON DIOXIDE

Abstract

Abstract: N-formylation of carbon dioxide (CO₂) is the reaction of CO₂with organic amine in the presence of a reducing agent to form N-formamide compound. The N-formylation reaction of CO₂ can be used as a resources to reduce greenhouse gas emissions, andcan convert cheap CO₂ into highvalue-added organic chemicals such as N,N-dimethylformamide and N-formylmorpholine,etc., expandsthe CO₂ downstream conversion and utilization of the reaction network. Inthis paper,the catalyst system, catalytic mechanism, and reaction process of N-formylation of CO₂ in recent yearswere reviewed, and the problems in the research and future developmentof the reactionwere also discussed.

Key words: CO₂, N-formylation, catalyst, reaction technology

References

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