Petroleum Processing and Petrochemicals ›› 2017, Vol. 48 ›› Issue (3): 68-74.

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SELECTIVITY OF HYDRO-PROCESSES FOR POLY-RING AROMATICS HYDROGENATION SATURATION ON Ni-Mo-W/Al2O3 AND Co-Mo/Al2O3 CATALYSTS

    

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  • Received:2016-08-22 Revised:2016-08-25 Online:2017-03-12 Published:2017-02-24
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Abstract: The influence of hydro-processing parameters on poly-ring aromatics saturation of FCC light cycle oil over Ni-Mo-W/γ-Al2O3 and Co-Mo/γ-Al2O3 catalysts was studied in a pilot plant. The results show that Ni-Mo-W catalyst has a higher aromatics saturation activity than Co-Mo catalyst at the same reaction temperature;the mono-ring aromatics selectivity and yield on Co-Mo catalyst is generally better than that of Ni-Mo-W catalyst; and the selective saturation performance of Ni-Mo-W catalyst is more susceptible to the processing parameters. To realize the high rate of poly-ring aromatics saturation and the maximization of mono-aromatics yield, lower reaction temperature is better for Ni-Mo-W catalyst, while Co-Mo catalyst is suitable for the reaction at moderate reaction temperature and higher reaction pressure.

Key words: FCC light cycle oil, aromatics, hydrogenation saturation, selectivity

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