石油炼制与化工
• 分析与评定 • 上一篇 下一篇
高枝荣 周继红 杨海鹰
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摘要: 常规催化裂化材料活性评价方法,产物都是在线收集、离线分析,只能计算平均转化率和产物分布,无法研究催化裂化材料在测定过程中的失活状况。为了给催化裂化材料裂化活性评价和失活研究提供更多的信息,本研究提出了一种催化裂化材料裂化活性和失活速率的评价方法——连续脉冲微反-色谱法。方法仅需5~30 mg的待评材料,即可在较短的时间内(单次评价时间不超过20 min)给出多种评价信息,得到常规评价方法无法得到的一些新的信息,具有评价信息丰富、准确、快速和经济的优点。
关键词: 脉冲微反-色谱, 催化裂化, 催化剂活性, 失活, 快速, 分析方法
Abstract: In conventional catalyst evaluation, products were off-line analyzed, and only average conversion and product distributions were provided without information about the proceeding of catalyst deactivation. In order to obtain more information from the catalyst evaluation, a new method, continuous pulse micro-reactor chromatography, was proposed and put into practice to observe the deactivation of catalyst. The new method could obtain various evaluation information in 20 min (per run), and it could provide some new understandings about the catalyst performance, which was impossible for the conventional methods. Only 5-30 mg sample was needed, and the test was accurate, fast and economic.
Key words: pulse micro-reactor chromatography, catalytic cracking, catalytic cracking, deactivation, fast, analytical method
高枝荣 周继红 杨海鹰. 连续脉冲微反-色谱法及其在催化裂化材料评价中的应用[J]. 石油炼制与化工, doi: .
. CONTINUOUS PULSE MICRO-REACTOR CHROMATOGRAPHY AND ITS APPLICATION IN FCC CATALYST EVALUATION[J]. Petroleum Processing and Petrochemicals, doi: .
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