石油炼制与化工

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神华煤炭直接液化项目氢气系统优化

吴秀章   

  1. 神华集团有限责任公司
  • 收稿日期:2007-11-29 修回日期:1900-01-01 出版日期:2008-06-12 发布日期:2008-06-12
  • 通讯作者: 吴秀章

OPTIMIZATION ON HYDROGEN SYSTEM OF SHENHUA DIRECT COAL LIQUEFACTION PROJECT

  • Received:2007-11-29 Revised:1900-01-01 Online:2008-06-12 Published:2008-06-12

摘要: 阐述了神华煤炭直接液化项目的氢气需求和为提高氢气利用率采取的措施。该项目采用两套干煤处理能力为2 000 t/d的煤气化制氢装置提供煤炭液化和液化油品加氢等所需的氢气。煤炭液化装置采用膜分离系统将循环氢的H2纯度从86.64%提高到96.95%,在满足第二液化反应器采用内循环的要求外,补充氢量从28.934t/h降低到19.186t/h。采用变压吸附装置(PSA)回收煤炭液化、溶剂加氢稳定和加氢改质装置的富氢排放气中的氢气。建议对PSA尾气中的氢气进一步回收利用,提高项目的氢气利用率。

关键词: 煤炭直接液化, 优化, 氢气

Abstract: This article analyzed the hydrogen requirement in Shenhua direct coal liquefaction project (SDCLP) and presented efforts in reducing hydrogen usage. In SDCLP, two coal gasifiers were used to provide hydrogen required for direct coal liquefaction and downstream oil hydrogenation processes. After deploying a membrane system at the outlet of cold high pressure separator, the hydrogen concentration of recycle gas increased from 86.6% to 97.0%. Thus, the consumption of make-up hydrogen could be greatly decreased from 28.93t/h to 9.19t/h, as well as the recycle cup operation of the second reactor was satisfied. Pressure Swing Adsorption (PSA) facility was also used to recover hydrogen from the hydrogen-rich off-gas discharged from coal liquefaction, solvent hydro-stabilization and hydro-upgrading units. In order to further increase hydrogen utilization, a suggestion of recovering hydrogen in the PSA tail gas was proposed.

Key words: direct coal liquefaction, optimization, hydrogen