石油炼制与化工

• 油品与添加剂 • 上一篇    下一篇

橡胶籽生物柴油氧化安定性及改性研究

秦敏;陈国需;许世海   

  1. 后勤工程学院油料应用与管理工程系
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2010-02-12 发布日期:2010-02-12
  • 通讯作者: 秦敏

INVESTIGATION ON THE OXIDATION STABILITY OF RUBBER SEED OIL BIODIESEL AND ITS IMPROVEMENT

  • Received:1900-01-01 Revised:1900-01-01 Online:2010-02-12 Published:2010-02-12

摘要: 对橡胶籽生物柴油用SH/T0690、SH/T0175、EN14112等方法,通过过氧化值、运动粘度、酸值、碘值、不溶物、诱导期等指标评价其氧化安定性。结果表明,氧化过程中橡胶籽生物柴油的过氧化值、运动粘度、酸值、不溶物增加,碘值降低,其中异辛烷不溶物比总不溶物量大很多,对于高度氧化的橡胶籽生物柴油与非极性物质如矿物柴油混合时应引起重视。同时,未经改性的橡胶籽生物柴油氧化安定性差,诱导期远远不能满足国家标准要求,但经添加抗氧剂进行改性后,橡胶籽生物柴油氧化安定性得到明显改善,诱导期完全能够满足国家标准要求。所研究的5种抗氧剂均能改善橡胶籽生物柴油的氧化安定性,其中抗氧剂BS100效果最好。

关键词: 橡胶籽生物柴油, 氧化安定性, 抗氧剂

Abstract: The oxidation stability of rubber seed oil (RSO) biodiesel was investigated by using SH/T0690, SH/T0175 and EN14112 test methods to observe the changes in peroxide value (PV), kinematic viscosity (KV), acid value (AV), iodine value (IV), insolubles and induction period. Results show that PV, KV, AV and insolubles of the RSO biodiesel increase, IV decreases during oxidation tests. The iso-octane insolubles are much higher than the total insolubles, which indicate that great attention should be paid when mixing RSO biodiesel with mineral diesel fuel. The oxidation stability of RSO biodiesel is poor, its induction period can not meet the requirement of National Standard for biodiesel, yet it could be improved by adding antioxidants significantly. With antioxidants the induction period of RSO biodiesel could well meet the requirement of National Standard. The tested five antioxidants all exhibit good effectiveness, and BS100 is the best.

Key words: rubber seed oil biodiesel, oxidation stability, antioxidant