石油炼制与化工

• 加工工艺 • 上一篇    下一篇

萃取法脱除工业戊烷中硫化物的萃取剂研究

柳艳修1,宋华1,江雪源2   

  1. 1. 大庆石油学院化学化工学院
    2. 大庆油田有限责任公司
  • 收稿日期:2009-10-22 修回日期:1900-01-01 出版日期:2010-06-12 发布日期:2010-06-12
  • 通讯作者: 柳艳修

INVESTIGATION ON THE EXTRATION AGENT FOR REMOVING SULFIDES FROM PENTANE

Liu Yan-xiu,SONG Hua   

  • Received:2009-10-22 Revised:1900-01-01 Online:2010-06-12 Published:2010-06-12
  • Contact: Liu Yan-xiu

摘要: 以工业戊烷为原料,在萃取温度15 ℃、静置时间15 min、剂油比为1:1的条件下,考察了多种萃取剂的萃取脱硫性能。实验结果表明,糠醛和NaOH溶液作为单一萃取剂的效果较好,可将工业戊烷中的硫由原来的40.3 mg/L降低到1mg/L; 5%NaOH溶液与95%乙醇在较宽的体积比范围内进行复配可将戊烷中硫含量降低到1mg/L; 当N,N-二甲基甲酰胺与5%NaOH溶液按照体积比为1:1进行复配时,可将戊烷中的硫含量降低到1 mg/L,但N,N-二甲基甲酰胺含量过高则会抑制复合萃取剂的脱硫效果。

关键词: 戊烷, 发泡剂, 萃取剂, 脱硫

Abstract: The desulfurization performance of several extraction agents were studied using industrial pentane as feed under the conditions of an extraction temperature of 15℃, a settling time of 15 min and an agent to oil ratio of 1. Test results indicated that: (1) As to single extraction agent, furfural and NaOH solution are preferred, which can reduce the sulfur content of pentane from 40.3 mg/L to 1.0 mg/L; (2) 5%NaOH solution and 95% ethanol could be formed composite agent in rather wide volume ratios, which can reduce the sulfur content of pentane to 1.0 mg/L; (3) Composite agent of DMF and 5%NaOH mixing with a volume ratio of 1 can reduce the sulfur content of pentane to 1.0 mg/L, yet exceeded amount of DMF in composite agent might suppress the removal of sulfides from pentane.

Key words: pentane, vesicant, extractor, desulfurization