石油炼制与化工

• 基础研究 •    下一篇

油煤共炼的理论基础及工艺过程优选

吴治国,龙军   

  1. 石油化工科学研究院
  • 收稿日期:2011-02-25 修回日期:1900-01-01 出版日期:2011-06-12 发布日期:2011-06-12
  • 通讯作者: 吴治国

THE THEORETICAL BASIS OF OIL-COAL CO-PROCESSING AND PROCESS OPTIMIZATION

Jun Long   

  • Received:2011-02-25 Revised:1900-01-01 Online:2011-06-12 Published:2011-06-12

摘要: 从原料油和煤的主要物化特征入手,描述了其热解和加氢热解的化学过程,在此基础上提出了采用两个反应器的新的工艺流程。油、煤热解过程有大量小分子烃类产生,从过程机理出发,选择合适的煤种,采取适当的措施便可以得到一定产率的轻质燃料油。油和煤的物化结构特征有差别,它们加氢热解生成的轻质燃油的组成不同,油加氢裂化生成的轻质燃油主要是大分子侧链及部分烷烃裂解产物;而来自煤的轻质燃油主要是单环、双环、三环芳烃,链烷烃量较少。油煤加氢共炼需要妥善应对原料油中胶质、沥青质热裂解带来的影响,避免其对煤热解造成负面影响。

关键词: 油煤共炼, 加氢裂化, 热解, 工艺过程

Abstract: This paper first described known thermal decomposition and hydrocracking processes using heavy oil and coal as feedstock respectively, where the characteristic and structural difference between crude and coal were presented. Studies showed that though fundamental differences observed between heavy oil and coal based thermal decomposition processes, the principle of free radical chain reactions was shared, which was the theoretical basis of oil-coal co-processing. It was reported that aromatics up to three-ring was mostly found in the hydrocracked products from coal feed; whereas segments from long paraffinic chain or aliphatic substituents in polycyclic aromatic hydrocarbons were the major components of oil based hydrocracked products. It should be noted that asphaltene and gum in heavy oil could favor the formation of coke and lower light oil yield during oil-coal co-processing, and the selection of suitable coal species was also significant. Based on the discussions, a two-stage reactors design was proposed for the co-processing process.

Key words: Oil and coal co-processing, hydrocracking, pyrolysis, process