石油炼制与化工

• 设备及防腐 • 上一篇    下一篇

阳离子沥青乳化剂的缓蚀行为研究

孔祥军1,马玲2,牛春革2,地力拜.马力克2   

  1. 1. 中国石油克拉玛依石化公司炼油化工研究院
    2. 中石油克拉玛依石化分公司炼油化工研究院
  • 收稿日期:2010-11-30 修回日期:2011-01-07 出版日期:2011-06-12 发布日期:2011-06-12
  • 通讯作者: 孔祥军

STUDY ON THE CORROSION INHIBITION BEHAVIOURS OF CATIONIC ASPHALT EMULSIFIERS

  • Received:2010-11-30 Revised:2011-01-07 Online:2011-06-12 Published:2011-06-12

摘要: 模拟施工现场腐蚀体系,以常压静态腐蚀失重法测定了pH值为2时的腐蚀速率为11.41g/(m2.h),研究了十种阳离子沥青乳化剂对金属的缓蚀作用。试验结果表明:咪唑啉类、烷基多胺类、烷基酰胺类和季铵盐类阳离子沥青乳化剂,对于盐酸为腐蚀介质的体系起到了很好的缓蚀作用,具有乳化和缓蚀的双重效用;采用扫描电镜法对阳离子沥青乳化剂的缓蚀行为及机理进行了研究,认为乳化剂在金属表面形成了吸附膜,从而延缓了腐蚀作用。

关键词: 阳离子, 沥青乳化剂, 缓蚀作用

Abstract: The corrosion inhibition behaviours of 10 cationic asphalt emulsifiers were studied by static weight loss test and simulating the corrosion system of emulsifying asphalt and paving. Results showed that some types of cationic asphalt emulsifiers including imidazoline, alkyl amines, alkyl amides and quaternary ammonium, exhibited excellent corrosion inhibition performance in hydrochloric acid corrosion system, possessing both emulsification and corrosion inhibition functions. Scanning electron microscopy was also used to study the corrosion inhibition behaviours of cationic asphalt emulsifiers and the inhibition mechanism was discussed. It was suggested that the adsorption of emulsifiers on the metal surface might form an adsorption film to prevent the contact of metal with the corrosion medium, thus the corrosion was inhibited.

Key words: cation, asphalt emulsifier, corrosion inhibition