石油炼制与化工
• 加工工艺 • 上一篇 下一篇
侯凯丽,李会鹏
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Kaili Hou,Huipeng Li
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摘要： 通过后合成法制备了KOH/SBA-15负载型固体碱催化剂，以大豆油和甲醇为原料，进行酯交换反应合成生物柴油。考察醇油比、反应温度、反应时间、活性组分负载量和催化剂用量等因素对生物柴油收率的影响。结果表明，当醇油摩尔比为16：1、反应温度为60 ℃、反应时间为8 h、活性组分KOH负载量（w）为15 %、催化剂用量为原料油质量的5％条件下，生物柴油收率为85.32 %。
关键词: 生物柴油, 固体碱, 氢氧化钾, 酯交换, SBA-15
Abstract: A solid base catalyst, KOH/SBA-15, was post-synthesized and used in the synthesis of biodiesel by transesterification of soybean oil and methanol. The influence of reaction conditions, such as molar ratio of methanol to oil (M/O), reaction temperature, reaction time, active component content and catalyst dosage on the biodiesel yield was studied. Results showed that under the conditions of M/O molar ratio of 16, a reaction temperature of 60 ℃, a reaction time of 8 h, an active component content of 15 % and a catalyst dosage of 5 % (based on oil), the yield of biodiesel reached 85.32 %.
Key words: biodiesel, solid base, KOH, transestirification, SBA-15
侯凯丽,李会鹏. KOH/SBA-15催化大豆油酯交换反应制备生物柴油[J]. 石油炼制与化工, doi: .
Kaili Hou,Huipeng Li. PREPARATION OF BIODIESEL BY TRANSESTERIFICATION OF SOYBEAN OIL OVER KOH/SBA-15 CATALYST[J]. Petroleum Processing and Petrochemicals, doi: .
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