石油炼制与化工 ›› 2013, Vol. 44 ›› Issue (10): 1-7.

• 基础研究 •    下一篇

烷烃催化制丙烯研究进展

李福超,张久顺,袁起民   

  1. 中国石化石油化工科学研究院
  • 收稿日期:2013-04-09 修回日期:2013-05-04 出版日期:2013-10-12 发布日期:2013-09-22
  • 通讯作者: 袁起民 E-mail:yuanqm.ripp@sinopec.com

ADVANCES IN CATALYTIC PROCESSING OF PARAFFIN FOR PROPYLENE PRODUCTION

  • Received:2013-04-09 Revised:2013-05-04 Online:2013-10-12 Published:2013-09-22

摘要: 烷烃催化制低碳烯烃是增产丙烯的新途径。本文阐述了蒸汽裂解技术的现有问题,综述了催化裂解与催化氧化催化剂体系和反应规律的研究进展,并对两种路径的技术状况和发展趋势进行了分析。催化裂解的发展方向是开发新型分子筛催化剂,使烷烃可以在较低的反应温度下发生裂解,实现增产低碳烯烃而降低干气产率的目标。深入研究催化脱氢作用机理,开发低温高选择性催化剂,加强反应体系的工艺研究是催化氧化实现工业化的关键。

Abstract: Catalytic conversion of paraffin to light alkenes is a new route for maximizing propylene production. Existing problems of steam pyrolysis were summarized. Research advances in catalyst and reaction behavior of catalytic pyrolysis and catalytic oxidation was reviewed, respectively, including discussion on current situations and developing tendency. It seems that in order to enhance alkene yields and further decrease dry gas yield the development of new zeolite catalysts which allow paraffin to crack at lower temperature is the main target of catalytic pyrolysis. In addition, it is essential for commercialization of catalytic oxidation to intensify studies on catalytic mechanism and catalysts with low temperature activity and high selectivity and strengthen the process research at the same time.