石油炼制与化工 ›› 2013, Vol. 44 ›› Issue (10): 67-72.

• 催化剂 • 上一篇    下一篇

催化裂化汽油芳构化降烯烃催化剂的改进研究

王晓1,霍东亮1,余济伟2,李国萍2   

  1. 1. 中国石油抚顺石化公司催化剂厂

      2. 中国石油抚顺石化公司研究院
  • 收稿日期:2013-03-08 修回日期:2013-03-30 出版日期:2013-10-12 发布日期:2013-09-22
  • 通讯作者: 余济伟 E-mail:yujiwei@petrochina.com.cn

IMPROVEMENT OF AROMATIZATION AND OIEFIN-REDUCTION CATALYST FOR FCC HEAVY GASOLINE

  • Received:2013-03-08 Revised:2013-03-30 Online:2013-10-12 Published:2013-09-22

摘要: 针对催化裂化汽油加氢脱硫降烯烃组合工艺技术中,芳构化降烯烃辛烷值恢复催化剂(M)应用于重馏分汽油加氢时,存在因反应温度高而影响催化剂长周期运行及液体总收率等问题,对催化剂进行了优化升级改进研究,在M催化剂的基础上,通过对HZSM-5分子筛原料改进及调变活性金属组分,研制出活性高、稳定性好的催化裂化重汽油芳构化降烯烃辛烷值恢复催化剂M -Ⅱ。催化剂的活性评价结果表明,与M催化剂相比,在烯烃降低幅度大致相当的情况下,采用M -Ⅱ催化剂时,芳烃含量增加1.3百分点,RON提高0.7个单位。

Abstract: The aromatization and olefin-reduction catalyst M had been applied in commercial unit for desulfurization and olefin-reduction process of FCCG heavy fraction. To overcome the shortcomings of lower liquid yield and shorter cycle length at higher reaction temperature, a series of modification procedures were taken to improve the activity and stability of the catalyst M. A modified catalyst M-II was then successfully developed by improving manufacture of HZSM-5 and the ratio of the active metals. The results of the performance test of M-II, compared with that of catalyst M, show that aromatics increases more than 1.3 % and RON is 0.7 higher than M at the close reduction level of olefin.