基础油对复合磺酸钙基∕钛基润滑脂性能的影响

石油炼制与化工 ›› 2013, Vol. 44 ›› Issue (11): 81-85.

基础油对复合磺酸钙基∕钛基润滑脂性能的影响

毛大恒,周明,石琛,毛向辉

中南大学机电工程学院高性能复杂制造国家重点实验室

收稿日期:2013-04-09 修回日期:2013-05-08 出版日期:2013-11-12 发布日期:2013-10-29
通讯作者: 周明 E-mail:zhouming0507@163.com
基金资助:
教育部博士点专项基金;中南大学博士后基金;国家自然科学基金

EFFECT OF BASE OIL ON TRIBOLOGICAL PROPERTIES OF CALCIUM SULFONATE COMPLEX & TITANIUM-BASED COMPOSITE GREASE

Received:2013-04-09 Revised:2013-05-08 Online:2013-11-12 Published:2013-10-29

摘要/Abstract

摘要： 探讨了用不同类型基础油制备复合磺酸钙基∕钛基润滑脂的工艺过程，分析了不同基础油对复合磺酸钙基∕钛基润滑脂理化性能和摩擦学性能的影响，结果表明：酯系和醇酯系合成油不能用来制备出复合磺酸钙基∕钛基润滑脂；用高温链条矿物油、聚α烯烃合成油和二甲基硅油均能顺利制备出稳定的复合磺酸钙基∕钛基润滑脂，但其综合性能不高，未能获得满意效果。在综合性能测试和台架试验的基础上，发现用KP6030高黏度矿物油与二甲基硅油的混合体制备的复合磺酸钙基∕钛基润滑脂不仅具有高滴点、高油膜强度、高烧结载荷和优良的机械剪切性能，而且其蒸发量小、高温稳定性好，台架工作寿命长，是制备高温润滑脂理想的基础油。

Abstract: The processes of preparation of calcium sulfonate complex & titanium-based composite grease with different base oils are studied, and the effect of base oil on physic-chemical properties and tribological properties of the composite grease is analyzed. The results show that the base oils of synthetic ester and polyol ester have high flash point and high viscosity, but they can’t be converted into grease; however high temperature chain mineral oil, poly α-olefin and methyl silicone oils can all be smoothly thickened into grease, but the performances are not satisfied. Based on the test of comprehensive properties of the greases and bearing bench testing, it is found that the calcium sulfonate complex & titanium-based composite grease made from the mixture of KP6030 high viscosity mineral oil and methyl silicone oil has high dropping point, high oil film strength, high sintering load and excellent mechanical shear performance, less evaporation, good high temperature stability, long bench working life, so the mixture is a better base oil for the manufacture of calcium sulfonate & titanium-based composite grease.

毛大恒周明石琛毛向辉. 基础油对复合磺酸钙基∕钛基润滑脂性能的影响[J]. 石油炼制与化工, 2013, 44(11): 81-85.

参考文献

[1] 李雪静，潘元青.润滑脂工业发展概况[J].汽车工艺与材料，2003，12:1～3.
[2] 刘显秋.高碱性磺酸盐复合钙基润滑脂的发展简述[C]//全国第十二届润滑脂技术交流会论文集.北京：石油学报（石油加工），2003：8～15.
[3] 龙在安.复合磺酸钙基润滑脂的研究[C]//全国第十二届润滑脂技术交流会论文集.北京：石油学报（石油加工），2003：10～14.
[4] 益建国.复合磺酸钙基润滑脂的结构组成及应用[J].汽车工艺与材料，2005（3）：50～54.
[5] Muir R J.High Performance Calcium Sulfonate Complex Lubricating Grease[J]. NLGI Spokesman (National Lubricating Grease Institute), Jul, 1988, 52(4): 140～146.
[6] Mackwood W,Muir R.Calcium sulfonate grease...one decade later[J].NLGI Spokesman (National Lubricating Grease Institute), 1999, 63(5):24～27.
[7] Mackwood W,Muir R,Dunn W.Calcium sulfonate complex grease the next generation food machinery grease[J].NLGI Spokesman, May, 2003, 67(2) :17～21.
[8] Giasson S, Espinat D, Palermo T. Study of Microstructural Transformation of Overbased Calcium Sulphonates During Friction[J].Lubrication Science, 1993, 5(2): 91～111.
[9] Kimura Y,Takemura K,Araki J,et al.Study of synthetic oil based calcium sulfonate complex greases[J].NLGI Spokesman,2006,70(9):20-26
[10] Kobylyanskii1 E V,Kravchuk1 G G,Makedonskii1 O A.Structure of Ultrabasic Sulfonate Greases[J].Chemistry and Technology of Fuels and Oils,2002,38(2):110-114
[11] EVGEN K,OLEG M, YURI I. The overbased lubricating grease: reglarities and peculiarities of properties[J].Chemistry and chemical technology,2011,5(2):231-239
[12] ZHEN Zhong-Wen, YAN Qiu-Xia, XIN Feng.Tribological properties of the overbased calcium suifonate complex greases[J].Applied Mechanics and Materials,2012,130-134:891-894
[13] 刘巧红，毛大恒，俸颢. 改性复合磺酸钙基脂的研究[J]．润滑与密封，2007，32（2）：142～144.
[14] 黄精忠.复合磺酸钙基脂的结构探讨和性能研究.润滑与密封[J]，1996（1）：37～44.
[15] 张林雅.磺酸钙基脂的研制[J].腐蚀科学与防护技术，2007,19(2),134-136
[16] Borisenko1 L I,Ishchuk1 Y L.Properties of polyurea greases on a synthetic base[J].Chemistry and Technology of Fuels and Oils,2004,40(6):415-417
[17] John S,Faci J,Hocine F,Bob C.Steel mill greases: Evaluation and analysis[J].NLGI Spokesman,2005,69(8):8-13