石油炼制与化工 ›› 2013, Vol. 44 ›› Issue (6): 17-21.

• 基础研究 • 上一篇    下一篇

动态热结垢法评价重油混合稳定性研究

戈丹妮,王嘉玮,陈坤,王宗贤   

  1. 中国石油大学(华东)重质油国家重点实验室
  • 收稿日期:2012-10-16 修回日期:2012-11-30 出版日期:2013-06-12 发布日期:2013-05-24
  • 通讯作者: 王宗贤 E-mail:zxwang@upc.edu.cn
  • 基金资助:

    中国石油天然气集团公司项目

STUDY ON STABILITY OF BLENDING HEAVY OILS BY DYNAMIC THERMAL FOULING METHOD

  • Received:2012-10-16 Revised:2012-11-30 Online:2013-06-12 Published:2013-05-24

摘要: 借鉴污垢热阻的思路建立了用于评价混合重油稳定性的动态热结垢法,以兰州减压渣油为原料,通过试验确定评价装置的主要操作条件,即反应器外壁温度390 ℃、流体流速10 g/min和操作时间30 h,并针对兰州减压渣油、兰州乙烯裂解油及其混合体系进行了混合重油稳定性评价试验研究。结果表明:重油混合体系中,随着乙烯裂解油加入量增加,在反应器内壁上形成的污垢热阻变大,温降数增大,体系的稳定性下降;所得结论与质量分数电导率法的评价结果相吻合,说明动态热结垢法可以动态地跟踪重油混合体系相分离和结垢情况,为工业上重油的合理掺炼提供了一定的依据。

Abstract: A method of dynamic thermal fouling was created to evaluate the stability of blended heavy oil. Using Lanzhou Vacuum Residue as stock, the evaluation conditions were discussed. Under the conditions of flow rate of 10 g/min, reactor wall temperature of 390 ℃ and sampling at 30 h, the reliable evaluation results can be obtained. The method was then used to examine the stabilities of Lanzhou Vacuum Residue (LZVR) with Lanzhou Ethylene Tar (LZET) blending system. The evaluation results that the fouling resistance and the temperature drop in reactor center from the wall increase with the increment of the ratio of LZET/LZVR indicate the decrease of stability of blending system. The results of the method are consistent with the analysis of mass fraction normalized conductivity. This demonstrate that dynamic thermal fouling method can track the phase separation and fouling of blended heavy oil dynamically, which provides supports for industrial blending process.