石油炼制与化工 ›› 2014, Vol. 45 ›› Issue (5): 21-24.

• 基础研究 • 上一篇    下一篇

氢初压对塔河沥青质加氢反应过程的影响

韩忠祥,孙昱东,杨朝合   

  1. 中国石油大学(华东)化学工程学院
  • 收稿日期:2013-11-27 修回日期:2013-12-22 出版日期:2014-05-12 发布日期:2014-04-22
  • 通讯作者: 孙昱东 E-mail:ydsun@upc.edu.cn
  • 基金资助:

    国家自然科学基金项目;中央高校基本科研业务费专项基金项目;中国石油科技创新基金项目

INFLUENCE OF INITIAL HYDROGEN PRESSURE ON ASPHALTENE HYDROCONVERSION

  • Received:2013-11-27 Revised:2013-12-22 Online:2014-05-12 Published:2014-04-22

摘要: 以十氢萘为溶剂,在高压釜内考察了氢初压对塔河常压渣油沥青质(正庚烷不溶物)加氢转化反应过程的影响。结果表明:氢初压由8.0 MPa增加到14.0 MPa时,(气体+汽油)收率增加,焦炭产率降低,而沥青质的转化率、柴油收率均先增加后降低,在12 MPa时出现最大值,渣油收率先降低后增加在12 MPa时出现最小值;在一定范围内,氢初压的增加有利于沥青质的加氢转化,但过高的氢初压会导致催化剂表面的油膜厚度增加,阻碍反应物向催化剂表面扩散,不利于沥青质的加氢反应;随着氢初压的增加,硫、氮脱除率增加,加氢后沥青质的平均相对分子质量降低,但变化幅度均随氢初压的增加而减小。

Abstract: The influence of initial hydrogen pressure on hydroconversion of C7-insoluble asphaltene in THAR (Tahe atmospheric residue) was studied by autoclave with decalin as a solvent. The results show that the yield of gas plus gasoline increases, the coke yield decreases when the initial hydrogen pressure increases from 8.0 MPa to 14.0 MPa. The maximum asphaltene conversion and diesel yield and the minimum hydrotreated residue are obtained at 12.0 MPa. The increase of initial hydrogen pressure is beneficial to the conversion of asphaltene, but the exorbitant initial hydrogen pressure has adverse effect to the conversion because the oil-film on catalyst become thicker and is harmful to the diffusion of reactant into catalyst. With the increase of initial hydrogen pressure, the desulfurization rate, denitrification rate, and the molecule weight of hydrotreated asphaltene are decreased, but the change decreases with the increase of hydrogen pressure.