Abstract: Fine grain NaZSM-5 zeolites with wide range of Si/Al ratio were prepared by using proper amount of template, tetraethyl orthosilicate（TEOS）and water. The effect of preparation parameters on the performance of the catalysts containing ZSM-5 was studied by XRD，SEM，NH3-TPD，BET techniques and MTP test. The optimal conditions for synthesis of ZSM-5 zeolite are: n(TPA+)/n(SiO2) of 0.16-0.18，H2O/SiO2 mass ration of 14-16, Si/Al ratio of 500 and crystallization temperature of 130～150 ℃. The catalysts containing ZSM-5 were obtained by extrusion, acid exchange and calcination, and evaluated for MTP. The results indicate that the catalyst containing ZSM-5 with Si/Al ratio of 500 has a good performance of MTP. The methanol conversion is higher than 99%, and the propylene selectivity can be maintained at about 45%.