石油炼制与化工 ›› 2015, Vol. 46 ›› Issue (4): 7-11.

• 基础研究 • 上一篇    下一篇

油砂沥青油的加氢处理研究

王雅兰1,关明华2,张会成2,马波1   

  1. 1. 辽宁石油化工大学
      2. 中国石化抚顺石油化工研究院
  • 收稿日期:2014-10-09 修回日期:2014-12-29 出版日期:2015-04-12 发布日期:2015-03-20
  • 通讯作者: 张会成 E-mail:zhanghuicheng.fshy@sinopec.com
  • 基金资助:

    中国石油化工股份有限公司合同项目

RESEARCH ON HYDROTREATMENT OF OIL SANDS BITUMEN

  • Received:2014-10-09 Revised:2014-12-29 Online:2015-04-12 Published:2015-03-20

摘要: 油砂沥青油为高密度、高黏度、高金属含量、高残炭的劣质原料,采用沸腾床加氢催化剂,利用反应釜进行加氢处理,考察了反应温度和反应时间对其反应性能的影响,以寻求最佳的沸腾床加氢处理反应条件。实验结果表明,随着反应温度升高、反应时间增加,油砂沥青油的加氢生成油中Fe,Na,Ni,V含量和残炭逐渐降低,最佳反应条件为反应温度430 ℃、反应时间80min,在该条件下,Fe,Na,Ni,V的脱除率分别为99.97%,99.99%,98.11%,99.61%,残炭降低率为72.61%。利用沸腾床进行油砂沥青油的加氢处理,可以有效改善油品性质,满足深加工要求。

Abstract: The oil sands bitumen is an inferior raw material with high density, high viscosity, and high content of metal and carbon residue(CCR). The impact of reaction temperature and reaction time on hydrotreating performance of oil sands bitumen was investigated with an autoclave and ebullated bed hydrotreating catalyst to find the optimal hydrotreating conditions. The test results show that as the temperature and reaction time increases, contents of Fe, Na, Ni, V, and CCR decrease. High temperature promotes the removal of metal and reduction of carbon residue. The best reaction conditions are: a temperature of 430 ℃ and a reaction time of 80min. Under the best conditions, the removal rates of Fe, Na, Ni, V reach 99.97%,99.99%,98.11%,99.61%, respectively. And the reduction rate of carbon residue is 72.61%. It is concluded that the ebullated bed hydrotreating is an effective technology for deep processing oil sands bitumen.