巯基苯并噻唑醇在菜籽油和加氢油中的摩擦学性能

石油炼制与化工 ›› 2015, Vol. 46 ›› Issue (4): 72-77.

巯基苯并噻唑醇在菜籽油和加氢油中的摩擦学性能

熊丽萍¹,穆琳¹,周响¹,仇建伟²

1. 华东交通大学理学院
2. 中国石油兰州润滑油研究开发中心

收稿日期:2014-09-19 修回日期:2014-12-02 出版日期:2015-04-12 发布日期:2015-03-20
通讯作者: 熊丽萍 E-mail:121264099@qq.com
基金资助:
国家自然科学基金;江西省自然科学基金;江西省教育厅科技计划

TRIBOLOGICAL PROPERTIES OF MERCAPTOBENZOTHIAZOLE ALCOHOL AS ADDITIVE IN RAPESEED OIL AND HYDROTREATED OIL

Received:2014-09-19 Revised:2014-12-02 Online:2015-04-12 Published:2015-03-20

摘要/Abstract

摘要： 以脂肪醇和巯基苯并噻唑为原料，合成了3-(2-巯基-苯并噻唑基)-2-乙氧基丙醇(TBE)，在四球摩擦试验机上考察了TBE单剂以及其与磷酸三丁酯（TBP）组合的复配添加剂在菜籽油（RSO）和加氢油（5Cst）中的摩擦学性能。结果表明：合成的TBE具有一定的摩擦学性能，且在RSO中响应效果优于在5Cst中；在基础油中添加TBE/TBP复配剂可以获得协同增效的作用，复配剂的极压、抗磨和减摩性能均优于单剂，且TBE与TBP质量比7:3和5:5为最佳配比，TBE/TBP复配剂在RSO中的响应效果也优于在5Cst中。

Abstract: A lubricant additive 3-(benzo[d]thiazol-2-ylthio)-2-ethoxypropan-1-ol (TBE) was synthesized using fatty alcohol and a mercaptobenzothiazole as starting materials. The tribological properties of TBE alone and TBE/TBP (tributyl phosphate) composite additive in rapeseed oil (RSO) and hydrotreated base oil with 5Cst (5Cst) were investigated using a four-ball friction tester. The results show that the synthesized TBE has some tribological properties, and the response effect in RSO is better than in 5 cst. On the other hand, the addition of TBE and TBP simultaneously in base oil can get synergies. TBE/TBP has better extreme pressure, anti-wear and friction properties than the single additive, and the best mass ratio of TBE/TBP composite additive is 7:3 or 5:5. The response performance of TBE/TBP composite additive in RSO is also better than in 5Cst.

熊丽萍穆琳周响仇建伟. 巯基苯并噻唑醇在菜籽油和加氢油中的摩擦学性能[J]. 石油炼制与化工, 2015, 46(4): 72-77.

参考文献

[1]方建华,陈波水,董凌,等.硼氮化改性菜籽油润滑添加剂的摩擦学性能研究[J].石油炼制与化工,2004,35(1):29-33.
[2]Yang Hanmin, He Dongping. Prospect of Environmental Friendly Lubricants Made from Vegetable Oils[J]. China Oils and Fats,2003,28(11):65-67.
[3]XiaoZhixin , Shi Chen, Mao Daheng. Effect of Tocopherol on Antioxygenic Properties of Green Lubricating Oil[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed,2008,23(3):289-292.
[4]Adhvaryu A, Erhan SZ. Tribological studies of thermally and chemically modi?ed vegetable oils for use as environmentally friendly lubricants[J]. Wear,2004;257:359-67.
[5]L.A. Quinchia, M.A. Delgado, T. Reddyhoff, C. Gallegos, H.A. Spikes. Tribological studies of potential vegetable oil-based lubricants containing environmentally friendly viscosity modi?ers[J]. Tribology International,2014,69: 110-117.
[6]尤建伟,李芬芳,黄伊辉.含硼苯并噻唑酯类化合物在菜籽油中的摩擦学性能研究[J].石油炼制与化工,2009,40(11):52-56.
[7]He Zhongyi, Xiong Liping, Qian Liang, Han Sheng, Qiu Jianwei, Fu Xisheng. Tribological properties and hydrolysis stability study of benzothiazole borate derivative[J]. Lubrication Science,2014,26(2):81-94.
[8]李久盛,王永刚,孙令国,等.含巯基苯并噻唑官能团润滑油添加剂的制备及其摩擦学性能[J].材料保护,2010,43(12):28-30.
[9]曾小军,李芬芳,周茂林,等.2-巯基苯并噻唑的改性及其在菜籽油中的摩擦学性能研究[J].石油学报(石油加工),2007,23(6):97-99.
[10]何忠义.硼酸衍生物润滑油添加剂的研究进展[J].华东交通大学学报, 2011,28(1):1-6.
[11]李为民,任朋飞,段伟娜.脂肪酸甲酯型含氮硼酸酯的合成及摩擦学性能研究[J].石油炼制与化工,2012,43(6):71-74.
[12]黄伊辉.,李芬芳.,尤建伟,等.含轻基二硫代氨基甲酸衍生物在菜籽油中的摩擦学性能, [J].石油炼制与化工,2010,41(3):60-64.
[13]Xiangqiong Zeng, Hua Wu, Hongling Yi, Tianhui Ren. Tribological behavior of three novel triazine erivatives as additives in rapeseed oil[J]. Wear,2007, 262(5-6): 718~726.
[14]苏克曼,潘铁英,张玉兰.波谱解析[M].上海:华东理工大学出版社, 2002: 80~132.
[15]曹月平,余来贵.磷酸三甲酚酯和亚磷酸二正丁酯添加剂对菜籽油摩擦学性能的影响[J].摩擦学学报.2000,2(20):119-122.
[16]刘晶郁,张永,王毓民.磷酸酯与其它添加剂在菜籽油中摩擦相互作用研究[J].润滑与密封.2004,3(2):36-39.
[17]何忠义,吴余琴,熊丽萍,等.改性菜籽油的制备及其摩擦学性能研究[J].华东交通大学学报,2014,31(4):105-110.
[18]乔玉林,方学敬,党鸿辛.硫磷系极压抗磨添加剂的发展动态[J].润滑与密封，1994(6):56-59．
[19]李久盛,等.苯并三氮唑及其衍生物在菜籽油中的摩擦学性能研究[J].摩擦学学报,2001,21(3):187-190.
[20]Zeng Xiang qiong, Li Jing, Wu Xue dong,et al. The Tribological Behaviors of Hydroxyl-Containing Dithiocarhamate-triazine Derivatives Additives in Rapeseed Oil[J]．Tribology International.2007,40:560-566．
[21]范成凯,李芬芳,周茂林,等.多功能三聚氯氰衍生物润滑油添加剂的研究现状[J].润滑油.2008,23(6):1-4.
[22]饶文琦,任天辉,李久盛.六元含氮杂环化合物的分子结构对其抗磨性能的影响[J].摩擦学学报,2001,21(2):118-120.
[23]乔玉林,池俊成,徐滨士,马世宁.几种磷氮型润滑油添加剂的摩擦行为及其摩擦化学机制的研究[J].石油炼制与化工,2002,33(3):14-16.
[24] Xiong Liping，He Zhongyi，Qian Liang，Mu Lin, Chen Aixi, Han Sheng, Qiu Jianwei, Fu Xisheng. Synthesis of a benzotriazole borate derivative and study of tribological properties and hydrolysis stability[J].PLOS ONE,2014,9 (1): 83501.