石油炼制与化工 ›› 2016, Vol. 47 ›› Issue (12): 41-44.

• 催化剂 • 上一篇    下一篇

钒对催化裂化催化剂的影响及新型捕钒剂的应用

沈海军,王明胜   

  1. 中国石化扬子石油化工有限公司
  • 收稿日期:2016-05-18 修回日期:2016-06-04 出版日期:2016-12-12 发布日期:2016-11-29
  • 通讯作者: 沈海军 E-mail:shenhj01.yzsh@sinopec.com
  • 基金资助:
     

EFFECT OF VANADIUM ON FCC CATALYST AND APPLICATION OF NEW ANTI-VANADIUM CATALYST

    

  1.  
  • Received:2016-05-18 Revised:2016-06-04 Online:2016-12-12 Published:2016-11-29
  • Supported by:
     

摘要: 从重金属钒对催化裂化催化剂污染机理入手,分析了高钒原料对催化裂化催化剂以及产品分布的影响。针对中国石化扬子石油化工有限公司2.0 Mt/a催化裂化装置原料油中钒含量高的情况,试用中国石化石油化工科学研究院最新开发的CGP-1YZ型专用抗钒催化剂。工业应用结果表明,与装置原用催化剂相比,CGP-1YZ型催化剂具有良好的抗钒能力,使用抗钒催化剂后,转化率和汽油产率分别增加9.51和5.67百分点,焦炭选择性显著改善,催化剂单耗降低了0.15 kg/t。

关键词: 催化裂化, 钒, 催化剂, 钒捕剂

Abstract: Based on the deactivation mechanism of FCC catalyst by vanadium, this paper analyzed the influence of V on catalyst performance and product distribution on processing the high vanadium feedstocks. The new anti-vanadium FCC catalyst CGP-1YZ, developed by SINOPEC Research Institute of Petroleum Processing, was used in the No.2 FCC unit with capacity of 2 Mt/a in Yangzi Petrochemical Company. The industrial application results show that compared with the original catalyst, the new catalyst shows a good anti-vanadium ability, the conversion and gasoline yield increase by 9.51 and 5.67 percentage points, respectively. The catalyst consumption lowers 0.15 kg/t. The coke selectivity is significantly improved.

Key words: catalytic cracking, vanadium, catalyst, V-trap agent

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