石油炼制与化工 ›› 2016, Vol. 47 ›› Issue (2): 1-4.

• 基础研究 •    下一篇

铝溶胶对碳钢腐蚀性的研究

孙敏,田辉平,刘宇键,许昀   

  1. 中国石化石油化工科学研究院
  • 收稿日期:2015-09-09 修回日期:2015-08-08 出版日期:2016-02-12 发布日期:2016-01-29
  • 通讯作者: 孙敏 E-mail:sunm.ripp@sinopec.com

STUDY OF CORROSION ON CARBON STEEL BY ALUMINUM SOL

  • Received:2015-09-09 Revised:2015-08-08 Online:2016-02-12 Published:2016-01-29

摘要:

通过测量碳钢挂片浸渍在铝溶胶中的失重程度,考察了铝溶胶的腐蚀性,并对腐蚀产物进行了红外光谱和扫描电镜表征,确定腐蚀产物包括α-FeOOH、γ-FeOOH和Fe3O4,分析和研究了碳钢在铝溶胶中腐蚀产物的形成过程,并说明铝溶胶中氯离子的存在能够改变钝化膜的结构,从而加速碳钢的腐蚀。

关键词: 铝溶胶, 碳钢, 腐蚀性, 腐蚀产物

Abstract:

The corrosion of aluminum sol on carbon steel was studied through the weightlessness of the steel sample soaked in the sol. The corrosion products were characterized by means of IR and SEM, and the formation mechanism of the corrosion products was analyzed. It is discovered that the corrosion products are mainly composed of α-FeOOH, γ-FeOOH and Fe3O4, and the presence of chloride ions in aluminum sol destroys the structure of the passivation film on the surface of the carbon steel to accelerate the corrosion of carbon steel, resulting in the formation of corrosion products.

Key words: aluminum sol, carbon steel, corrosion, corrosion product