›› 2016, Vol. 47 ›› Issue (5): 46-50.

• 催化剂 • 上一篇    下一篇

NJBMDA-Ⅱ催化剂在白油加氢脱芳烃装置的工业应用

王文丰   

  1. 南京炼油厂有限责任公司
  • 收稿日期:2015-09-21 修回日期:2015-11-24 出版日期:2016-05-12 发布日期:2016-04-25
  • 通讯作者: 王文丰 E-mail:wangwf.jlsh@sinopec.com

COMMERCIAL APPLICATION OF NJBMDA-Ⅱ CATALYS TIN WHITE OIL DEAROMATIZATION UNIT

  • Received:2015-09-21 Revised:2015-11-24 Online:2016-05-12 Published:2016-04-25

摘要: 介绍了白油加氢脱芳烃工艺技术和NJBMDA-Ⅱ型高效芳烃加氢催化剂在南京炼油厂有限责任公司白油加氢脱芳烃装置上的工业应用情况。工业应用结果表明:NJBMDA-Ⅱ型催化剂的低温活性好,在初始反应温度125 ℃左右即有很强的活性,液相体积空速高;在反应器入口温度135 ℃、氢分压2.0 MPa、体积空速1.0 h-1、氢油体积比400的工况下,反应生成油中芳烃质量分数小于0.1%,生产工艺流程和控制过程简单可靠,可满足低芳烃环保型精制白油产品的规模生产需求,具有较好的经济效益。

关键词: 加氢, 脱芳烃, 催化剂, 白油, 低温活性

Abstract: This article introduces the production engineering of and the application of high efficiency benzene hydrogenation catalyst NJBMDA-Ⅱ in this unit. The result shows that NJBMDA-Ⅱ has good activity at low temperature, with strong activity at initial temperature around 125 ℃. It also has high liquid phase space velocity, strong dearomatizing performance, high production efficiency. At conditions of 135 ℃,hydrogen partial pressure of 2.2 MPa, LHSV of 1.0 h-1 and H2/oil volume ratio of 400, aromatic content is less than 1% in the product oil. The production and control process is simple and reliable, which is able to meet the scale production demand of environment-friendly refined white oil with low aromatic content. The unit has fine economic benefit.

Key words: hydrogenation, dearomatization, catalyst, white oil, low temperature activity