石油炼制与化工 ›› 2016, Vol. 47 ›› Issue (8): 20-24.
• 催化剂 • 上一篇 下一篇
马洋,吴浩,马雪鸿,张博
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摘要:
分析了中国石化抚顺石油化工研究院研制的FH-98与FH-40C 催化剂在中国石油克拉玛依石化有限责任公司450 kt/a焦化汽油加氢装置上的应用情况。结果表明:2种催化剂均具有优异的加氢脱硫、脱氮效果,精制汽油符合重整装置预加氢原料要求;由于FH-98催化剂具有一定裂化性能,易导致反应器床层温度大幅度波动或飞温,反应器工艺操作风险较高;使用FH-40C催化剂时,床层反应温度控制较为平和,安全操作性能较好。
关键词: FH-98, FH-40C, 催化剂, 焦化汽油, 加氢
Abstract:
The performance of FH-98 and FH-40C catalyst developed by FRIPP in a 450 kt/a coking gasoline hydrogenation unit of PetroChina Karamay Petrochemical Co. Ltd.was compared. The results indicate that both catalysts displayed excellent activity in hydrodesulfurization (HDS) and hydrodenitrogenation (HDN). The qualities of the hydrogenated gasoline in both cases meet the feedstock requirements for reforming pre-hydrogenation unit. As FH-98 catalyst has certain cracking performance, it is easy to cause large temperature fluctuations or runaway of the bed temperature, resulting in higher operation risk. In contrast the FH-40C catalyst is found to be safer in terms of sustaining a moderate reaction temperature due to its weaker cracking capability.
Key words: FH-98, FH-40C, catalyst, coker gasoline, hydrogenation
马洋 吴浩 马雪鸿 张博. FH-98与FH-40C催化剂在焦化汽油加氢装置上的应用对比[J]. 石油炼制与化工, 2016, 47(8): 20-24.
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