石油炼制与化工 ›› 2016, Vol. 47 ›› Issue (9): 18-22.
• 加工工艺 • 上一篇 下一篇
祝飞雄,王金龙
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摘要:
针对中国石化镇海炼化分公司PX联合装置加工外购碳八芳烃(C8A)带来的管路堵塞问题进行了深入分析并提出了解决方案。认为外购C8A在储运过程中混入的少量溶解氧诱导烯烃发生聚合反应导致结焦是管路堵塞的主要原因,结焦速率与温度、原料溴指数呈正相关关系。结焦吸附法简单易行,成本较低,可有效解决因加工外购C8A带来的设备堵塞问题,可用于同类装置解决或者预防类似问题。
关键词: 对二甲苯, 溶解氧, 结焦, 堵塞
Abstract:
The pipe blockage problems during operation of PX combination plant in Zhenhai Petrochemical Co. when processing purchased C8A were analyzed. It is concluded that the coke formation due to olefin polymerization induced by the small amount of oxygen dissolved in C8A during storage and transportation is the main cause. Coking rate is positively correlated with the temperature and bromine index of the purchased C8A. A simple and cheap coking adsorption method was suggested and proved to be effective for solving the blockage problems during processing purchased C8A. It can be used for similar equipment to solve or to prevent similar problems.
Key words: para-xylene, dissolved oxygen, coking, blockage
祝飞雄 王金龙. 镇海炼化加工外购碳八芳烃存在的问题及对策[J]. 石油炼制与化工, 2016, 47(9): 18-22.
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