石油炼制与化工 ›› 2017, Vol. 48 ›› Issue (2): 53-56.

• 基础研究 • 上一篇    下一篇

减压渣油掺炼焦化蜡油的焦化反应研究

李世松1,舒畅1,宋国良1,王栋2   

  1. 1. 中海油天津化工研究设计院有限公司
    2. 中海油炼化有限责任公司惠州炼油分公司
  • 收稿日期:2016-08-02 修回日期:2016-09-05 出版日期:2017-02-12 发布日期:2017-01-17
  • 通讯作者: 李世松 E-mail:lss851228@163.com
  • 基金资助:
     

COKING REACTION OF VACUUM RESIDUE MIXED WITH COKING GAS OILS

    

  1.  
  • Received:2016-08-02 Revised:2016-09-05 Online:2017-02-12 Published:2017-01-17
  • Supported by:
     

摘要: 以国内某炼油厂减压渣油为焦化原料,选用该厂焦化蜡油作为供氢剂,并将焦化蜡油切割成小于400 ℃馏分(A)、400~430 ℃馏分(B)和430~460 ℃馏分(C)3个窄馏分,测定了3个窄馏分的结构参数和供氢指数,并在相同的反应条件下,在减压渣油中分别掺炼质量分数10%的3个窄馏分,考察了各焦化产物的收率,并与纯减压渣油焦化反应进行了对比。结果表明:3个窄馏分供氢指数由大到小的顺序为A>B>C;掺炼窄馏分A的焦化反应液体收率明显高于纯减压渣油焦化反应;在3个窄馏分中,掺炼A时的液体收率最高,掺炼B时次之,掺炼C时最低,这与3个窄馏分供氢指数的测定结果一致。

关键词: 供氢剂, 焦化蜡油, 窄馏分, 供氢能力

Abstract: A vacuum reside was chosen as a coking feed. Three narrow cuts: <400 ℃(A), 400-430 ℃(B) , and 430—460 ℃(C) of the coking gas oil in the same refinery were used as hydrogen donors. The hydrogen-donating indexes and structure parameters of three narrow fractions were measured. Under the same coking conditions, the product yields of the residue blending with 10% narrow cut respectively were examined and compared with the results of pure residue without narrow cut. The order of hydrogen-donating indexes of three narrow fractions is A>B>C. The same order is for liquid yields for residue blending with three cuts. While the yield of liquid product of vacuum residue with cut A is higher than the pure residue.

Key words: hydrogen donor, coking gas oil, narrow fractions, hydrogen-donating ability

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