›› 2017, Vol. 48 ›› Issue (6): 20-24.

• 催化剂 • 上一篇    下一篇

低焦炭高效重油转化FCC催化剂的开发与工业应用

潘志爽,袁程远,张爱萍,滕秋霞   

  1. 中国石油兰州化工研究中心
  • 收稿日期:2016-11-11 修回日期:2016-12-09 出版日期:2017-06-12 发布日期:2017-05-24
  • 通讯作者: 潘志爽 E-mail:panzhishuang@126.com
  • 基金资助:
    中国石油天然气股份有限公司资助项目

DEVELOPMENT AND APPLICATION OF LOW COKE AND EFFICIENT CONVERSION RFCC CATALYST

  • Received:2016-11-11 Revised:2016-12-09 Online:2017-06-12 Published:2017-05-24

摘要: 采用新型基质材料和酸性调变技术制备了低焦炭高效重油催化裂化催化剂,用N2吸附-脱附和程序升温氨脱附(NH3-TPD)方法对催化剂进行了表征,并在实验室和工业提升管反应器中对催化剂的性能进行了评价。结果表明:研制的催化剂具有比表面积高、介孔体积大、强酸中心少、弱酸中心多等特点。实验室评价结果显示,与对比催化剂相比,该催化剂的重油收率降低1.37百分点,焦炭产率下降0.26百分点。工业应用结果表明,该催化剂具有重油转化能力强、焦炭选择性好的特点。

关键词: 催化裂化, 重油, 焦炭, 催化剂

Abstract: The catalytic cracking catalyst with low coke-making and high heavy oil conversion was prepared using new matrix material and acidity modification technology. The catalytic cracking catalyst was characterized by means of nitrogen adsorption/desorption and temperature-programmed desorption of ammonia (NH3-TPD) techniques. The catalytic cracking performance of the catalyst was evaluated in a FCC riser reactor. The results indicated that compared with the catalyst in using, the prepared catalyst had the advantages of higher surface area, mesoporous volume, lower strong acid sites and higher weak acid sites. Laboratory evaluation results showed that compared with the catalyst in using, the heavy oil yield and coke yield of the prepared catalyst decreased by 1.37 and 0.26 percentage points respectively. The industrial application results showed that the catalyst possessed the characteristics of strong heavy oil conversion ability and good coke selectivity.

Key words: catalytic cracking, heavy oil, coke, catalyst