石油炼制与化工 ›› 2017, Vol. 48 ›› Issue (9): 36-39.

• 基础研究 • 上一篇    下一篇

木粉在超临界甲醇中的液化研究

胡见波,杜泽学   

  1.  中国石化石油化工科学研究院

  • 收稿日期:2017-03-09 修回日期:2017-04-07 出版日期:2017-09-12 发布日期:2017-08-25
  • 通讯作者: 胡见波 E-mail:hujb.ripp@sinopec.com
  • 基金资助:
     

LIQUEFACTION OF WOOD POWDER IN SUPERCRITICAL METHANOL

  1.  
  • Received:2017-03-09 Revised:2017-04-07 Online:2017-09-12 Published:2017-08-25
  • Contact: Jianbo Hu E-mail:hujb.ripp@sinopec.com
  • Supported by:
     

摘要: 以木粉和甲醇为原料,在高压反应釜中进行木粉在超临界甲醇中的液化分解反应,研究甲醇与木粉的配比、反应时间、反应压力、催化剂种类及用量对木粉分解率、气化率和液化率的影响。结果表明,以NaOH为催化剂,在甲醇与木粉质量比为4.5、反应温度为320 ℃、反应时间为1 h的条件下,木粉液化率达到43.3%。

关键词: 生物质, 高压液化, 超临界, 甲醇

Abstract: The liquefaction of wood powder in supercritical methanol was investigated under different reaction conditions. The results indicate that the liquefaction, decomposition and gasification rate of wood powder were affected by the ratio of methanol to wood powder, reaction temperature and time, as well as type and amount of catalyst. At the best conditions: methanol to wood powder ratio of 4.5, 320℃, reaction time 1 h, and NaOH as catalyst, the liquefaction rate achieves 43.3%.

Key words: bio-mass, high pressure liquefaction, supercritical fluid, methanol

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