石油炼制与化工 ›› 2017, Vol. 48 ›› Issue (9): 78-83.

• 节能减排 • 上一篇    下一篇

DCC-气体分离装置热集成方案分析评价

陈璟仪,王侃,张冰剑,陈清林   

  1. 中山大学化学工程与技术学院 广东省石化过程节能工程技术研究中心
  • 收稿日期:2017-03-15 修回日期:2017-05-23 出版日期:2017-09-12 发布日期:2017-08-25
  • 通讯作者: 陈清林 E-mail:chqlin@mail.sysu.edu.cn
  • 基金资助:
    国家自然科学基金项目

ANALYSIS AND EVALUATION OF HEAT INTEGRATION SCHEMES FOR DEEP CATALYTIC CRACKING AND GAS SEPARATION UNITS

    

  1.  
  • Received:2017-03-15 Revised:2017-05-23 Online:2017-09-12 Published:2017-08-25
  • Contact: Qing-Lin CHEN E-mail:chqlin@mail.sysu.edu.cn
  • Supported by:
     

摘要: DCC (Deep Catalytic Cracking)是一种多产丙烯的深度重油催化裂解工艺。与常规的催化裂化装置相比,DCC装置的吸收稳定系统和下游的气体分离(简称气分)装置需要更多的中低温位热量。因此,DCC与气分装置的热集成方案对装置的低温余热系统、蒸汽产耗平衡和冷却负荷有着重要的影响。采用火用分析方法,借助流程模拟工具及能级-热量图,量化分析了DCC与气分装置的2种热集成方案,包括基于循环热媒水的直接热联合方案,以及基于热泵工艺的热联合方案。与直接热联合方案相比,热泵方案的换热过程?损可减少13.1%,1.0 MPa蒸汽消耗量可降低20 t/h;但是直接热集成方案的设备投资低。结果表明,DCC和气分装置中低温热源热阱的优化匹配是提高装置用能效率的重要因素。

关键词: DCC, 气体分离, 热集成, 热泵

Abstract: DCC (Deep Catalytic Cracking) is a catalytic conversion process derived from the FCC (Fluid Catalytic Cracking) process, using heavy feedstocks for producing more propylene. The absorption-stabilization system of DCC unit and the gas separation unit followed requires more low-grade heat, compared with the conventional FCC unit. Hence, the heat integration schemes of DCC and gas separation unit have significant impacts on the low-grade waste heat recovery, steam balance and cooling duty. In this paper, exergy analyses with two heat integration schemes of DCC and gas separation units, including the direct heat integration scheme based on circulating hot water, and the scheme based on the heat pump process, are presented using process simulation software and ε-Q diagram. The analysis results show that the heat integration scheme based on the heat pump process can reduce 13.1% exergy loss of heat exchange process and the consumption of 1.0 MPa steam 20 t/h, but needs higher equipment investment costs. According to the study, the optimal matching of low-grade heat sources and sinks in DCC and gas separation units is a vital factor of increasing the energy efficiency.

Key words: DCC, gas separation, heat integration, heat pump

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